Radiation cross-linking of montmorillnite/polypropylene composite
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Radiation cross-linking of montmorillnite/polypropylene composite
Journal of Radiation Research and Radiation ProcessingVol. 29, Issue 6, Pages: 345-348(2011)
作者机构:
1.浙江省能源与核技术应用研究院 杭州 310012
2.浙江大学化学工程联合国家重点实验室 杭州 310027
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WANG Yongchang, FAN Hong, MAO Yongyong, et al. Radiation cross-linking of montmorillnite/polypropylene composite. [J]. Journal of Radiation Research and Radiation Processing 29(6):345-348(2011)
DOI:
WANG Yongchang, FAN Hong, MAO Yongyong, et al. Radiation cross-linking of montmorillnite/polypropylene composite. [J]. Journal of Radiation Research and Radiation Processing 29(6):345-348(2011)DOI:
Radiation cross-linking of montmorillnite/polypropylene composite
采用熔融共混法制备了聚丙烯(Polypropylene,PP)/蒙脱土预辐射复合材料,通过X射线衍射(X-ray deffraction,XRD)和透射电子显微镜(Transmission electron microscope,TEM)对复合材料中蒙脱土的分散状态进行了表征,在空气氛围下利用电子束辐照对复合材料进行辐照交联,研究了交联剂在辐照中起的作用和蒙脱土对辐照交联的影响。结果表明:没有加入交联剂的PP不能交联,在PP中加入了蒙脱土以后,在一定的辐照剂量下可以促进PP的交联,含有蒙脱土PP交联体系的力学性能得到大幅度提高。
Abstract
Polypropylene/montmorillonite composite was prepared via melt compounding process. The dispersion of montmorillonite in the composite was analized by XRD (X-ray deffraction) and TEM (Transmission electron microscope). Electronic radiation was applied to make the composite radiation closs-linked in air. The effect of cross-linking agent and montmorillnite on the properties of polypropylene cross-linking was studied. The results indicated that cross-linking did not take place in absence of cross-linking agent, while in presence of both cross-linking agent and montmorillonite polypropylene cross-linking occurred in certain absorbed dose range. The cross-linked polypropylene/momtmorillnite composite exhibited improved mechanical properties.