Study of lauryl methacrylate emulsion polymerization by γ-rays irradiation and its oil absorption performances
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Study of lauryl methacrylate emulsion polymerization by γ-rays irradiation and its oil absorption performances
Journal of Radiation Research and Radiation ProcessingVol. 27, Issue 4, Pages: 201-206(2009)
作者机构:
1.中国科学技术大学化学与材料学院高分子科学与工程系 软物质化学重点实验室 合肥 230026
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ZHAO Weiliang, WANG Mozhen, TANG Gang, et al. Study of lauryl methacrylate emulsion polymerization by γ-rays irradiation and its oil absorption performances. [J]. Journal of Radiation Research and Radiation Processing 27(4):201-206(2009)
DOI:
ZHAO Weiliang, WANG Mozhen, TANG Gang, et al. Study of lauryl methacrylate emulsion polymerization by γ-rays irradiation and its oil absorption performances. [J]. Journal of Radiation Research and Radiation Processing 27(4):201-206(2009)DOI:
Study of lauryl methacrylate emulsion polymerization by γ-rays irradiation and its oil absorption performances
In this paper, a high-oil- absorption resin was prepared through the emulsion polymerization of lauryl methacrylate with additive of a small amount of N-hydroxymethyl acrylamide and acrylic acid, OP-10 and sodium lauryl benzenesulfate as the emulsifier, and initiated by γ-rays. Characterization analysis of the sample was carried out by FTIR, SEM and TG. SEM image shows that the morphology of the micelles from the polymer emulsion is regular, and the average particle size is about 170 nm. Polymer remains queit stable below 300,o,C. The influence of reaction conditions such as total absorbed dose, dose rate, solids content, N-hydroxymethyl acrylamide and acrylic acid content on kerosene absorption performances of the polymer has been studied. The maximal saturated oil absorbed ratio (g/g) of kerosene, chloroform and dimethyl benzene is 18.1, 19.5, and 15.3, respectively.