Preparation of amidoximated nylon 66 fibers for selective adsorption of uranium in simulated nuclear industry effluents

Mingxing ZHANG; Rong LI; Zhe XING; Jiangtao HU; Guozhong WU

doi:10.11889/j.1000-3436.2017.rrj.35.040304

您当前的位置：

首页 >

文章列表页 >

Preparation of amidoximated nylon 66 fibers for selective adsorption of uranium in simulated nuclear industry effluents

RADIATION CHEMISTRY | 更新时间：2021-12-10

- Preparation of amidoximated nylon 66 fibers for selective adsorption of uranium in simulated nuclear industry effluents
- Journal of Radiation Research and Radiation Processing Vol. 35, Issue 4, (2017)
- 作者机构：
  
  1.中国科学院上海应用物理研究所嘉定园区上海 201800
  2.中国科学院大学北京 100049
  3.上海科技大学上海 200031
- 作者简介：
- 基金信息：
  
  the National Natural Science Foundation of China(11275252);the National Nature Science Foundation of China(11305243);the National Nature Science Foundation of China(11405249);the National Nature Science Foundation of China(11605275);the National Nature Science Foundation of China(11675247)
- DOI：10.11889/j.1000-3436.2017.rrj.35.040304
  CLC：
扫描看全文
Mingxing ZHANG, Rong LI, Zhe XING, et al. Preparation of amidoximated nylon 66 fibers for selective adsorption of uranium in simulated nuclear industry effluents. [J]. Journal of Radiation Research and Radiation Processing 35(4):040304-8(2017)
DOI：

Mingxing ZHANG, Rong LI, Zhe XING, et al. Preparation of amidoximated nylon 66 fibers for selective adsorption of uranium in simulated nuclear industry effluents. [J]. Journal of Radiation Research and Radiation Processing 35(4):040304-8(2017) DOI： 10.11889/j.1000-3436.2017.rrj.35.040304.

摘要

结合辐射接枝聚合和化学修饰，通过三步处理，成功地制备了偕胺肟化尼龙66纤维。通过傅里叶红外光谱（Fourier transform infrared spectroscopy, FTIR）仪和扫描电子显微镜（Scanning electron microscopy, SEM）对初始的和修饰后的尼龙66纤维进行化学结构和微观形貌表征。结果表明，偕胺肟基团以共价方式连接到尼龙66纤维上。通过模拟核工业废水的吸附研究表明，PA66-,g,-PGMA-IDPAO纤维对铀酰离子有高的吸附效率（91.3%）和吸附选择性，具有巨大的潜在工业应用价值。

Abstract

Amidoximated nylon 66 fibers were successfully synthesized by combining radiation-induced graft polymerization with chemical modification through a three-step approach. The chemical structure and micromorphology of the pristine and modified nylon 66 fibers were characterized by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The results showed that amidoxime groups were covalently connected to nylon 66 fibers. The results of adsorption of uranium in simulated nuclear industry effluents showed that amidoximated nylon 66 fibers performed a high adsorption efficiency (91.3%) and excellent selectivity for uranium adsorption, indicating that amidoximated nylon 66 fibers have potential application in industry.

关键词

辐射接枝聚合尼龙66纤维偕胺肟化吸附铀酰离子模拟核工业废水

Keywords

Radiation-induced graft polymerizationNylon 66 fibersAmidoximationAdsorptionUraniumSimulated nuclear industry effluents

references

P D Bhalara , D Punetha , K Balasubramanian . A review of potential remediation techniques for uranium (Ⅵ) ion retrieval from contaminated aqueous environment . Journal of Environmental Chemical Engineering , 2014 . 2 (3 ):1621 -1634 . DOI:10.1016/j.jece.2014.06.007http://doi.org/10.1016/j.jece.2014.06.007 .

J Hu , H Ma , Z Xing , 等 . Preparation of amidoximated ultrahigh molecular weight polyethylene fiber by radiation grafting and uranium adsorption test . Industrial & Engineering Chemistry Research , 2015 . 55 (15 ):4118 -4124 . DOI:10.1021/acs.iecr.5b03175http://doi.org/10.1021/acs.iecr.5b03175 .

林莹 , 高柏 , 李元锋 . 核工业低浓度含铀废水处理技术进展 . 山东化工 , 2009 . 38 (3 ):35 -38 . http://www.cnki.com.cn/Article/CJFDTOTAL-SDHG200903011.htmhttp://www.cnki.com.cn/Article/CJFDTOTAL-SDHG200903011.htm, .

Ying LIN , Bai GAO , Yuanfeng LI . Development of study on treatment technology for wastewater with Low-level uranium content of nuclear industry . Shandong Chemical Industry , 2009 . 38 (3 ):35 -38 . http://www.cnki.com.cn/Article/CJFDTOTAL-SDHG200903011.htmhttp://www.cnki.com.cn/Article/CJFDTOTAL-SDHG200903011.htm, .

孙勇飞 , 郭合帅 , 郑明 , 等 . 尼龙-66滤膜电子束预辐照接枝丙烯酸的研究 . 辐射研究与辐射工艺学报 , 2014 . 32 (2 ):020302 DOI:10.11889/j.1000-3436.2014.rrj.32.020302http://doi.org/10.11889/j.1000-3436.2014.rrj.32.020302http://www.j.sinap.ac.cn/fushe/CN/abstract/abstract105.shtmlhttp://www.j.sinap.ac.cn/fushe/CN/abstract/abstract105.shtml, .

Yongfei SUN , Heshuai GUO , Ming ZHENG , 等 . Study on graft of acrylic acid to nylon-66 induced by electron beam pre-irradiation . Journal of Radiation Research and Radiation Processing , 2014 . 32 (2 ):020302 DOI:10.11889/j.1000-3436.2014.rrj.32.020302http://doi.org/10.11889/j.1000-3436.2014.rrj.32.020302http://www.j.sinap.ac.cn/fushe/CN/abstract/abstract105.shtmlhttp://www.j.sinap.ac.cn/fushe/CN/abstract/abstract105.shtml, .

于洋 , 蒋海青 , 李林繁 , 等 . 尼龙滤布共辐射接枝N-异丙基丙烯酰胺研究 . 辐射研究与辐射工艺学报 , 2012 . 30 (4 ):193 -197 . http://www.j.sinap.ac.cn/fushe/CN/abstract/abstract156.shtmlhttp://www.j.sinap.ac.cn/fushe/CN/abstract/abstract156.shtml, .

Yang YU , Haiqing JIANG , Linfan LI , 等 . Preparation of thermal responding textile using radiation grafting N-isopropylacrylamide onto nylon sieve . Journal of Radiation Research and Radiation Processing , 2012 . 30 (4 ):193 -197 . http://www.j.sinap.ac.cn/fushe/CN/abstract/abstract156.shtmlhttp://www.j.sinap.ac.cn/fushe/CN/abstract/abstract156.shtml, .

Y L Wang , L J Song , L Zhu , 等 . Removal of uranium (Ⅵ) from aqueous solution using iminodiacetic acid derivative functionalized SBA-15 as adsorbents . Dalton Transactions , 2014 . 43 (9 ):3739 -3749 . DOI:10.1039/C3DT52610Khttp://doi.org/10.1039/C3DT52610K .

T E Milja , V S Krupa , T P Rao . Synthesis, characterization and application of uranyl ion imprinted polymers of aniline and 8-hydroxy quinoline functionalized aniline . RSC Advances , 2014 . 4 (58 ):30718 -30724 . DOI:10.1039/C4RA04780Jhttp://doi.org/10.1039/C4RA04780J .

P A Kavaklı , N Seko , M Tamada , 等 . Radiation-induced graft polymerization of glycidyl methacrylate onto PE/PP nonwoven fabric and its modification toward enhanced amidoximation . Journal of applied polymer science , 2007 . 105 (3 ):1551 -1558 . DOI:10.1002/app.25023http://doi.org/10.1002/app.25023 .

段宇哲 , 张胜 , 谷晓昱 , 等 . 微波接枝改性尼龙66织物的阻燃性能 . 北京化工大学学报(自然科学版) , 2016 . 43 (2 ):19 -26 . DOI:10.13543/j.bhxbzr.2016.02.004.DUANhttp://doi.org/10.13543/j.bhxbzr.2016.02.004.DUAN .

Yuzhe DUAN , Sheng ZHANG , Xiaoyu GU , 等 . Enhancing the flame retardancy of nylon 66 fabric by microwave induced grafting with glycidyl methacrylate and 6H-dibenz(C, E) (1, 2) oxaphosphorin-6-oxide (DOPO) . Journal of Beijing University of Chemical Technology (Natural Science) , 2016 . 43 (2 ):19 -26. .

T Caykara , F Çakar , S Demirci . Preparation of amidoxi-mated poly (glycidyl methacrylate) microbeads . Polymer International , 2011 . 60 (1 ):141 -145 . DOI:10.1002/pi.2923http://doi.org/10.1002/pi.2923 .

I H Park , J C Jung , S C Hwang , 等 . Preparation and uranyl ion adsorptivity of macroreticular chelating resins containing phosphono groups . Macromolecular Materials and Engineering , 1992 . 197 (1 ):117 -129 . DOI:10.1002/apmc.1992.051970110http://doi.org/10.1002/apmc.1992.051970110 .

I H Park , J M Suh . Preparation and uranyl ion adsorptivity of macroreticular chelating resins containing a pair of neighboring amidoxime groups in a monomeric styrene unit . Die Angewandte Makromolekulare Chemie , 1996 . 239 (1 ):121 -132 . DOI:10.1002/apmc.1996.052390111http://doi.org/10.1002/apmc.1996.052390111 .

P A Kavaklı , N Seko , M Tamada , 等 . Adsorption efficiency of a new adsorbent towards uranium and vanadium ions at low concentrations . Separation Science and Technology , 2005 . 39 (7 ):1631 -1643 . DOI:10.1081/SS-120030785http://doi.org/10.1081/SS-120030785 .

Y Zhao , J Li , L Zhao , 等 . Synthesis of amidoxime-functionalized Fe3O4@SiO2 core-shell magnetic microspheres for highly efficient sorption of U (Ⅵ) . Chemical Engineering Journal , 2014 . 235 275 -283 . DOI:10.1016/j.cej.2013.09.034http://doi.org/10.1016/j.cej.2013.09.034 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation of NWF-g-DMC@Al₂O₃ adsorbent by preradiation grafting-embedding and its application for removal of chlorite

Radiation modification of mesoporous SiO₂ and its adsorption performance for rhenium

Preparation of amidoximated polyethylene nonwoven fabric and its uranium adsorption performance

Modified clinoptilolite adsorption of Sr(Ⅱ) in aqueous solutions

Synthesis of magnetic zeolite and its adsorption capability for Cs ions

Related Author

No data

Related Institution

Hubei Industrial Technology Research Institute of Intelligent Health, Hubei University of Science and Technology

College of Nuclear Technology and Chemical Biology, Hubei University of Science and Technology

School of Stomatology and Optometry, Hubei University of Science and Technology

School of Pharmacy, Hubei University of Science and Technology

School of Nuclear Science and Technology, University of Science and Technology of China

⁰