Phosphate-functionalized ultrahigh-molecular-weight polyethylene fiber: preparation and uranium adsorption performance

JIN Changxian; SHAO Dadong; GAO Qianhong

doi:10.11889/j.1000-3436.2022-0126

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Phosphate-functionalized ultrahigh-molecular-weight polyethylene fiber: preparation and uranium adsorption performance

RADIATION CHEMISTRY | 更新时间：2023-04-20

- Phosphate-functionalized ultrahigh-molecular-weight polyethylene fiber: preparation and uranium adsorption performance
- Journal of Radiation Research and Radiation Processing Vol. 41, Issue 2, Pages: 20202(2023)
- 作者机构：
  
  1.南京理工大学环境与生物工程学院南京 210094
- 作者简介：
  
  JIN Changxian (male) was born in October 1998, and now he is a graduate student at Nanjing University of Science and Technology
  SHAO Dadong, doctoral degree, professor, E-mail: shaodadong@126.com
  GAO Qianhong, doctoral degree, Lecturer, E-mail: gaoqianhong@njust.edu.cn
- 基金信息：
  
  the National Natural Science Foundation of China(21976089;22176098)
- DOI：10.11889/j.1000-3436.2022-0126
  CLC：
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JIN Changxian, SHAO Dadong, GAO Qianhong. Phosphate-functionalized ultrahigh-molecular-weight polyethylene fiber: preparation and uranium adsorption performance. [J]. Journal of Radiation Research and Radiation Processing 41(2):020202(2023)
DOI：

JIN Changxian, SHAO Dadong, GAO Qianhong. Phosphate-functionalized ultrahigh-molecular-weight polyethylene fiber: preparation and uranium adsorption performance. [J]. Journal of Radiation Research and Radiation Processing 41(2):020202(2023) DOI： 10.11889/j.1000-3436.2022-0126.

摘要

通过预辐射接枝技术将甲基丙烯酸缩水甘油酯（GMA）引入到超高分子量聚乙烯（UHMWPE）纤维表面，然后与（2-氨基乙基）膦酸二乙酯进行开环反应，从而制备出应用于含铀废液处理的磷酸酯功能化超高分子量聚乙烯（UHMWPE-,g,-DEPP）纤维。采用X射线衍射仪（XRD）、傅里叶变换红外光谱仪（FTIR）、X射线光电子能谱（XPS）、热重分析仪（TGA）和扫描电镜（SEM）等对改性前后纤维表面的化学结构、组成、热稳定性以及微观形貌等性能进行表征分析。为了研究该纤维对含铀废液中微量铀的去除性能，重点考察了起始溶液pH、初始离子浓度、吸附时间和温度等因素的影响。实验结果表明：UHMWPE-,g,-DEPP在室温条件下8 h可达到吸附平衡；在25 ℃、pH=5.0、,m,/,V,=0.2 g/L的条件下吸附量达到最大（113.2 mg/‍g）。该吸附过程遵循准二级动力学模型和Langmuir等温吸附模型，且该纤维表现出良好的循环使用性能和吸附选择性能。

Abstract

Glycidyl methacrylate (GMA) was grafted onto an ultrahigh-molecular-weight polyethylene (UHMWPE) fiber through pre-irradiation grafting, and further modified with diethyl (2-aminoethyl) phosphonate. A novel type of phosphate-functionalized fiber (UHMWPE-,g,-DEPP) was successfully prepared for the separation and recovery of trace uranium in radioactive wastewater. The chemical structure, surface functional groups, stability, micro morphology, and other physical and chemical properties of the fiber materials were analyzed by X-ray diffraction, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and scanning electron microscopy. The principal factors affecting the U(VI) adsorption performance of the UHMWPE-,g,-DEPP fiber were investigated, including pH of the aqueous solution, contact time, temperature, and coexisting ions. The experimental results showed that UHMWPE-,g,-DEPP can achieve an adsorption equilibrium at room temperature within 8 h and the maximum adsorption capacity (113.2 mg/g) at 25 °C, pH = 5.0, and ,m,/,V, = 0.2 g/‍L. The adsorption kinetic pattern was in good agreement with the pseudo-second-order model, and the adsorption equilibrium follows the Langmuir isotherm model well. The phosphate-functionalized fiber showed good recycling and adsorption selectivity.

关键词

铀超高分子量聚乙烯（2-氨基乙基）膦酸二乙酯辐射接枝

Keywords

UraniumUltra high molecular weight polyethyleneDiethyl (2-aminoethyl) phosphonateRadiation grafting

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