Preparation of reactive flame retardant dimethly allylphosphonate and its grafting onto cotton fabric via ultraviolet light irradiation

YU Wenhui; TIAN Jialong; PAN Jiang; JIANG Chenchen; QI Zhenming; ZANG Chuanfeng; WANG Chunxia

doi:10.11889/j.1000-3436.2022-0133

您当前的位置：

首页 >

文章列表页 >

Preparation of reactive flame retardant dimethly allylphosphonate and its grafting onto cotton fabric via ultraviolet light irradiation

RADIATION CHEMISTRY | 更新时间：2023-08-29

- Preparation of reactive flame retardant dimethly allylphosphonate and its grafting onto cotton fabric via ultraviolet light irradiation
- Journal of Radiation Research and Radiation Processing Vol. 41, Issue 4, Pages: 40202(2023)
- 作者机构：
  
  1.南通大学纺织服装学院南通 226019
  2.盐城工学院纺织服装学院盐城 224001
  3.西安工程大学纺织科学与工程学院西安 710000
- 作者简介：
  
  YU Wenhui (female) was born in January 1998, and obtained her bachelor's degree in engineering from Yancheng Institute of Technology in 2020. Now she is a graduate student at Nantong University, majoring in flame retardant textiles
  WANG Chunxia, doctoral degree, professor, E-mail: cxwang@mail.dhu.edu.cn
- 基金信息：
- DOI：10.11889/j.1000-3436.2022-0133
  CLC：
扫描看全文
YU Wenhui, TIAN Jialong, PAN Jiang, et al. Preparation of reactive flame retardant dimethly allylphosphonate and its grafting onto cotton fabric via ultraviolet light irradiation. [J]. Journal of Radiation Research and Radiation Processing 41(4):040202(2023)
DOI：

YU Wenhui, TIAN Jialong, PAN Jiang, et al. Preparation of reactive flame retardant dimethly allylphosphonate and its grafting onto cotton fabric via ultraviolet light irradiation. [J]. Journal of Radiation Research and Radiation Processing 41(4):040202(2023) DOI： 10.11889/j.1000-3436.2022-0133.

摘要

以亚磷酸二甲酯和3-溴丙烯为原料，制备了反应型阻燃剂丙烯基磷酸二甲酯（DA）。利用N，N'-亚甲基双丙烯酰胺（MBA）交联剂，以安息香双甲醚为光引发剂，在365 nm紫外光照射下，引发DA接枝到棉织物上，对棉织物进行阻燃整理。研究DA和MBA的质量浓度对棉织物阻燃性能的影响。结果表明：棉织物阻燃性能随DA和MBA质量浓度的增加而提高，棉织物极限氧指数（LOI）可达27.2%，续燃时间和阴燃时间均为0 s，经20次洗涤后，LOI仍达24.5%。整理后棉织物具有更好的热稳定性能，阻燃整理对棉织物的拉伸性能无显著影响。

Abstract

Reactive flame-retardant dimethly allylphosphonate (DA) was prepared using dimethyl phosphite and 3-bromopropy and was grafted onto cotton fabric via ultraviolet (UV) irradiation using N,N'-Methylenebis (2-propenamide) (MBA) as a crosslinker and benzoin dimethyl ether as an initiator. The effects of DA and MBA mass concentrations on the flame retardancy of the cotton fabric were studied. The results indicated that the flame retardancy of the cotton fabric was proportionate to the mass concentrations of DA and MBA. The limiting oxygen index (LOI) of the cotton fabric could reach 27.2%, and the afterburning time and smoldering time were both 0 s. After 20 washing turns, the LOI could still reach 24.5%. The final cotton fabric exhibited better thermal stability, and the flame-retardant finishing demonstrated no significant effect on the tensile property of the cotton fabric.

关键词

丙烯基磷酸二甲酯紫外光阻燃性能棉织物

Keywords

Dimethly allylphosphonateUltraviolet lightFlame retardanceCotton fabric

references

Chavali K S, Pethsangave D A, Patankar K C, et al. Graphene-based intumescent flame retardant on cotton fabric[J]. Journal of Materials Science, 2020, 55(29): 14197-14210. DOI: 10.1007/s10853-020-04989-6http://dx.doi.org/10.1007/s10853-020-04989-6.

Chen S S, Li X, Li Y, et al. Intumescent flame-retardant and self-healing superhydrophobic coatings on cotton fabric[J]. ACS Nano, 2015, 9(4): 4070-4076. DOI: 10. 1021/acsnano.5b00121http://dx.doi.org/10.1021/acsnano.5b00121.

Sun L, Xie Y T, Wu J M, et al. A novel P/N-based flame retardant synthesized by one-step method toward cotton materials and its flame-retardant mechanism[J]. Cellulose, 2021, 28(5): 3249-3264. DOI: 10.1007/s10570-021-03728-7http://dx.doi.org/10.1007/s10570-021-03728-7.

Jiang Z M, Li H, He Y W, et al. Flame retardancy and thermal behavior of cotton fabrics based on a novel phosphorus-containing siloxane[J]. Applied Surface Science, 2019, 479: 765-775. DOI: 10.1016/j.apsusc. 2019.02.159http://dx.doi.org/10.1016/j.apsusc.2019.02.159.

Zhang A N, Zhao H B, Cheng J B, et al. Construction of durable eco-friendly biomass-based flame-retardant coating for cotton fabrics[J]. Chemical Engineering Journal, 2021, 410: 128361. DOI: 10.1016/j.cej.2020. 128361http://dx.doi.org/10.1016/j.cej.2020.128361.

Scudamore M J, Briggs P J, Prager F H. Cone calorimetry— a review of tests carried out on plastics for the association of plastic manufacturers in Europe[J]. Fire and Materials, 1991, 15(2): 65-84. DOI: 10.1002/fam. 810150205http://dx.doi.org/10.1002/fam.810150205.

Yang Z Y, Fei B, Wang X W, et al. A novel halogen-free and formaldehyde-free flame retardant for cotton fabrics[J]. Fire and Materials, 2012, 36(1): 31-39. DOI: 10.1002/fam.1082http://dx.doi.org/10.1002/fam.1082.

Nazir R, Gaan S. Recent developments in P(O/S)-N containing flame retardants[J]. Journal of Applied Polymer Science, 2020, 137(1): 47910. DOI: 10.1002/app.47910http://dx.doi.org/10.1002/app.47910.

Salmeia K A, Gaan S, Malucelli G. Recent advances for flame retardancy of textiles based on phosphorus chemistry[J]. Polymers, 2016, 8(9): 319. DOI: 10.3390/polym8090319http://dx.doi.org/10.3390/polym8090319.

Horrocks R A. Textile flammability research since 1980 — personal challenges and partial solutions[J]. Polymer Degradation and Stability, 2013, 98(12): 2813-2824. DOI: 10.1016/j.polymdegradstab.2013.10.004http://dx.doi.org/10.1016/j.polymdegradstab.2013.10.004.

Yuan D D, Yin H Q, Cai X F. Effect of a novel flame retardant containing silicon and nitrogen on the thermal stability and flame retardancy of polycarbonate[J]. Journal of Thermal Analysis and Calorimetry, 2013, 111(2): 1531-1537. DOI: 10.1007/s10973-012-2488-yhttp://dx.doi.org/10.1007/s10973-012-2488-y.

van der Veen I, de Boer J. Phosphorus flame retardants: properties, production, environmental occurrence, toxicity and analysis[J]. Chemosphere, 2012, 88(10): 1119-1153. DOI: 10.1016/j.chemosphere.2012.03.067http://dx.doi.org/10.1016/j.chemosphere.2012.03.067.

Li Q L, Wang X L, Wang D Y, et al. A novel organophosphorus flame retardant: synthesis and durable finishing of poly(ethylene terephthalate)/cotton blends[J]. Journal of Applied Polymer Science, 2010, 117(5): 3066-3074. DOI: 10.1002/app.32074http://dx.doi.org/10.1002/app.32074.

Wang S H, Liu J, Sun L, et al. Preparation of flame-retardant/dyed cotton fabrics: flame retardancy, dyeing performance and flame retardant/dyed mechanism[J]. Cellulose, 2020, 27(17): 10425-10440. DOI: 10.1007/s10570-020-03469-zhttp://dx.doi.org/10.1007/s10570-020-03469-z.

Duquesne S, Lefebvre J, Delobel R, et al. Vinyl acetate/butyl acrylate copolymers—part 1: mechanism of degradation[J]. Polymer Degradation and Stability, 2004, 83(1): 19-28. DOI: 10.1016/s0141-3910(03)00176-9http://dx.doi.org/10.1016/s0141-3910(03)00176-9.

陈雨洁, 李章亮, 王春霞, 等. 紫外光辐照引发接枝制备卤胺抗菌棉织物[J]. 辐射研究与辐射工艺学报, 2022, 40(3): 030203. DOI: 10.11889/j.1000-3436.2021-0007http://dx.doi.org/10.11889/j.1000-3436.2021-0007.

CHEN Yujie, LI Zhangliang, WANG Chunxia, et al. Preparation of N-halamine treated antibacterial cotton fabric via UV irradiation[J]. Journal of Radiation Research and Radiation Processing, 2022, 40(3): 030203. DOI: 10.11889/j.1000-3436.2021-0007http://dx.doi.org/10.11889/j.1000-3436.2021-0007.

中国纺织工业联合会. 纺织品燃烧性能试验氧指数法: GB/T 5454—1997[S]. 北京: 中国标准出版社, 1997.

China National Textile And Apparel Council. Textiles-Burning behaviour-Oxygen index method: GB/T 5454—1997[S]. Beijing: Standards Press of China, 1997.

中华人民共和国国家质量监督检验检疫总局. 纺织品燃烧性能垂直方向损毁长度、阴燃和续燃时间的测定: GB/T 5455—2014[S]. 北京: 中国标准出版社, 2014.

General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China. Textiles-Burning behaviour-Determination of damaged length, afterglow time and afterflame time of vertically oriented specimens: GB/T 5454—2014[S]. Beijing: Standards Press of China, 2014.

American Association of Textile Chemista and Colorists. Colorfastness to Laundering: Accelerated: AATCC 61—2013[S]. Beijing: China Textiles Press, 2013.

国家技术监督局. 纺织品织物拉伸性能第1部分: 断裂强力和断裂伸长率的测定条样法: GB/T 3923.1—1997[S]. 北京: 中国标准出版社, 1997.

The State Bureau of Quality and Technical Supervision. Textiles-Tensile properties of fabrics-Part 1: Determination of breaking force and elongation at breaking force-Strip method: GB/T 3923.1—1997[S]. Beijing: Standards Press of China, 1997.

Jiang D W, Sun C Y, Zhou Y N, et al. Enhanced flame retardancy of cotton fabrics with a novel intumescent flame-retardant finishing system[J]. Fibers and Polymers, 2015, 16(2): 388-396. DOI: 10.1007/s12221-015-0388-zhttp://dx.doi.org/10.1007/s12221-015-0388-z.

Dave H, Ledwani L, Chandwani N, et al. The removal of impurities from gray cotton fabric by atmospheric pressure plasma treatment and its characterization using ATR-FTIR spectroscopy[J]. The Journal of the Textile Institute, 2014, 105(6): 586-596. DOI: 10.1080/00405000.2013.827900http://dx.doi.org/10.1080/00405000.2013.827900.

Li S, Yan H X, Feng S Y, et al. Synthesis and characterization of a phosphorus-containing flame retardant with double bonds and its application in bismaleimide resins[J]. RSC Advances, 2015, 5(123): 101480-101486. DOI: 10.1039/C5RA15946Fhttp://dx.doi.org/10.1039/C5RA15946F.

Xu F, Zhang G X, Wang P, et al. A novel ε-polylysine-derived durable phosphorus-nitrogen-based flame retardant for cotton fabrics[J].Cellulose, 2021, 28(6): 3807-3822. DOI: 10.1007/s10570-021-03714-zhttp://dx.doi.org/10.1007/s10570-021-03714-z.

毋登辉, 李欣航, 赵培华. 反应型P-N膨胀型阻燃剂的合成及其在棉织物中的应用[J]. 精细化工, 2023, 40(5): 1136-1142. DOI: 10.13550/j.jxhg.20220737http://dx.doi.org/10.13550/j.jxhg.20220737.

WU Denghui, LI Xinhang, ZHAO Peihua. Synthesis of reactive P-N intumescence flame retardant and its application in cotton fabric[J]. Fine Chemicals, 2023, 40(5): 1136-1142. DOI: 10.13550/j.jxhg.20220737http://dx.doi.org/10.13550/j.jxhg.20220737.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation of N-halamine treated antibacterial cotton fabric via UV irradiation

Hydrophobic property of cotton-fabric modified by electron-beam irradiation

Effects of electron beam irradiation grafting on anti-wrinkle/water and oil repellency of cotton fabric

Related Author

No data

Related Institution

Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University

Jiangsu Engineering Technology Research Center for Functional Textiles, Jiangnan University

CTA-TE Chemicals Co., Ltd, Beijing

Jiangsu Engineering Technology Research Center of Functional Textiles, Jiangnan University

Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University

⁰