1.中国工程物理研究院核物理与化学研究所 绵阳 621900
2.贵州师范大学材料与建筑工程学院 贵阳 550014
黎阳,男,1982年8月出生,2008年7月于西南科技大学获工学硕士学位,材料学专业 E-mail: liyang3300@163.com
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黎阳, 许云书. 圆环形截面碳化硅纤维管的辐射化学法合成[J]. 辐射研究与辐射工艺学报, 2010,28(1):15-19.
LI Yang, XU Yunshu. Radiation chemical fabrication of tubular silicon carbide fibers[J]. Journal of Radiation Research and Radiation Processing, 2010,28(1):15-19.
为制备碳化硅(Silicon carbide, SiC)纤维管,本研究利用10 MeV 电子直线加速器产生的高能电子束在空气中辐照聚碳硅烷(Polycarbosilane, PCS)先驱丝。研究了辐照工艺、热处理温度、吸收剂量对制备SiC 纤维管的影响,并运用红外光谱分析对SiC 纤维管的辐射制备机理作了初步探讨。结果表明,合适的辐照工艺为每次定点辐照20 s,停车冷却5 min;最佳热处理温度为350℃;红外光谱分析表明,空气中的氧通过与PCS中的Si–H、Si–CH,3, 反应而被引入到辐照产物中,形成了Si–OH 和C=O 结构;在经热处理的先驱丝中有Si–O–Si,Si–C–Si 等桥联结构生成;吸收剂量介于2.0−3.5 MGy 之间的PCS 先驱丝均能制得SiC 纤维管,且管壁厚度随着吸收剂量的增加而逐渐增加。
In order to prepare silicon carbide(SiC) fiber tubes, polycarbosilane precursor(PCS) fibers were irradiated by 10 MeV electron beams(EB) under atmosphere. The effects of irradiation art, heat treatment temperature,and absorbed dose on the performance of SiC fiber tube have been discussed and the relevant mechanism was studiedusing IR spectra. The results show that the best irradiation technique is using irradiation time of 20s with an intervalof 5 min, and the best heat treatment temperature is 350°C. IR spectra analysis shows that the Si−H and Si−CH,3, react with oxygen induced into irradiated PCS to form the structures of Si−OH and C=O. And the bridge structures of Si−O−Si and Si−C−Si have been produced when the irradiated PCS fibers are treated in suitable temperatures. The SiC fiber tubes could be obtained from the precursor fibers with an absorbed dose of 2.0−3.5 MGy and treated by furanidine, and the thickness of the ceramic tube is dependent on the absorbed dose.In order to prepare silicon carbide(SiC) fiber tubes, polycarbosilane precursor(PCS) fibers were irradiated by 10 MeV electron beams(EB) under atmosphere. The effects of irradiation art, heat treatment temperature,and absorbed dose on the performance of SiC fiber tube have been discussed and the relevant mechanism was studiedusing IR spectra. The results show that the best irradiation technique is using irradiation time of 20s with an intervalof 5 min, and the best heat treatment temperature is 350°C. IR spectra analysis shows that the Si−H and Si−CH,3, react with oxygen induced into irradiated PCS to form the structures of Si−OH and C=O. And the bridge structures of Si−O−Si and Si−C−Si have been produced when the irradiated PCS fibers are treated in suitable temperatures. The SiC fiber tubes could be obtained from the precursor fibers with an absorbed dose of 2.0−3.5 MGy and treated by furanidine, and the thickness of the ceramic tube is dependent on the absorbed dose.
聚碳硅烷先驱丝电子束辐照SiC 纤维管
Polycarbosilane precursor fibersElectron beamIrradiationSilicon carbide fiber tubes
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