Zhang Wanxi, Sun Jiazhen. RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE-Ⅱ. KINETICS OF POLYMERIZATION REACTION[J]. Journal of Radiation Research and Radiation Processing, 1985,3(4):1-10.
Zhang Wanxi, Sun Jiazhen. RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE-Ⅱ. KINETICS OF POLYMERIZATION REACTION[J]. Journal of Radiation Research and Radiation Processing, 1985,3(4):1-10.DOI:
The kinetic model equations of radiation-induced emulsion polymerization of styrene have been established, according to the nucleation model suggested in above paper. The monomer conversion in stage of region Ⅱ for the polymerization reaction is given as follows:,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648356&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648373&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648357&type=,Where A——fraction of micellar nucleation;,B——fraction of aqueous nucleation.,The curve of monomer conversion against polymerrization time, number of polymer particles and degree of polymerization calculated by these model equations are in agreement with the experimental results.
关键词
苯乙烯辐射乳液聚合聚合反应动力学
Keywords
StyreneRadiation-induced emulsion polymerizationKinetics of polymerization reaction