1.上海交通大学,上海
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王铭钧, 殷明. 硅橡胶辐射交联研究Ⅰ溶胶分数与辐照剂量间的关系[J]. 辐射研究与辐射工艺学报, 1988,6(2):34-41.
Wang Mingjun, Yin Ming. STUDY OF THE RADIATION CROSSLINKING OF SILICONE RUBBER (Ⅰ)——THE RELATIONSHIP BETWEEN SOL FRACTION AND IRRADIATION DOSE[J]. Journal of Radiation Research and Radiation Processing, 1988,6(2):34-41.
硅橡胶的辐射交联,其溶胶分数和剂量的关系不符合Charlesby-Pinner关系,一般地认为,主要是由于裂解度和剂量不是一次方关系。如果考虑裂解度α和R,β,为线性关系,则可得,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648957&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648963&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648962&type=,即,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648965&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648968&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648966&type=,不是与R,而是与R,β,成线性关系。剂量指数,β,值主要受聚合物分子间束缚力和大分子主链的柔顺性的影响,凡能改变前述影响因素都会改变,β,值。本文研究了分子量、侧基和填料量等对,β,值的影响,同时,这些因素也影响了硅橡胶的凝胶剂量R,g,等其它交联参数。,正是由于影响,β,的因素是复杂的,我们从实验着手,考虑式(1)中A值一般较小,近似地,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648969&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648981&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648979&type=,以,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648984&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648986&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648972&type=,对lnR作图,从截距和斜率分别可得β值,再以,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649003&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649007&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648991&type=,对R,β,作图,可看出有相当的线性关系。,另外,以lnS对InR作图,外延至lnS=0,即S=1,则可得凝胶剂量R,g,,结合公式,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648994&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648997&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648995&type=,则可计算得到各交联参数。
In the process of radiation crosslinking of silicone rubber (SR), the relationship between sol fraction (S) and irradiation dose (R) does not conform to Charlesby-Pinner's formula, because α=α,1,+α,0,R assumed by Charlesby can not be established for SR. Generally, the exact equation may be described as follows,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648999&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649014&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649013&type=,Therefore, the relation between S and R for radiation crosslinking of SR can be obtained,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649015&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649017&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649016&type=,The influential factor is complicated for the dose exponent ,β, and molecular attraction between macromolecules and flexibility of main chain of polymer are important. If above factors were influenced,β, value can be changed. In this paper, the effect of molecular weight of polymer, side-group, filler and filler quantity on ,β, value and other crosslinking parameters were investigated.,Considering A is smaller in formula (2), we have,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649018&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649020&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649002&type=,By plotting with lnR ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649035&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649021&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649038&type=, against lnR, the value of B and β can be obtained from the intercept and the slope. Then, by plotting with ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649022&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649043&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649042&type=, against R, the linear relationship between them can be obtained.,Also, by plotting with lnS against lnR, and when lnS→O, gelation dose (Rg) can be obtained.,Combining with,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649044&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649023&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649045&type=,We can calculate the values of various crosslinking parameters
溶胶分数和剂量的关系影响因子聚合物的结构效应玻璃化转变温度聚合物分子量侧基填料和填料量
Relationship between sol fraction (S) and irradiation dose (R)Influential factorMolecular attractionFlexibility of main chainMolecular weight of polymerSide groupFiller and filler quantity
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