苯乙烯丁二烯共聚物和顺-1,4-聚异戊二烯的辐射交联以及与用硫磺的交联产物性能的比较

许云书; 孙颖; H. Siswono; 吉井文男; 幕内惠三; 隐冢裕之

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苯乙烯丁二烯共聚物和顺-1,4-聚异戊二烯的辐射交联以及与用硫磺的交联产物性能的比较

研究论文 | 更新时间：2023-04-23

- 苯乙烯丁二烯共聚物和顺-1,4-聚异戊二烯的辐射交联以及与用硫磺的交联产物性能的比较
- RADIATION CROSSLINKING OF STYRENE-BUTADIENE COPOLYMER AND cis-1,4-POLYISOPRENE CONTAINING FILLERS AND COMPARISON OF THEIR PROPERTIES WITH SULFUR VULCANIZATES
- 辐射研究与辐射工艺学报 1995年13卷第3期页码：156-160,155
- 作者机构：
  
  1.中国工程物理研究院核物理与化学所，成都　610003
  2.National Atomic Energy Agency, Indonesia
  3.日本原子力研究所高崎研究所
  4.日本化学品检查协会，东京
- 作者简介：
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许云书, 孙颖, H. Siswono, 等. 苯乙烯丁二烯共聚物和顺-1,4-聚异戊二烯的辐射交联以及与用硫磺的交联产物性能的比较[J]. 辐射研究与辐射工艺学报, 1995,13(3):156-160,155.

Xu Yunshu, Sun Ying, H. Siswono, et al. RADIATION CROSSLINKING OF STYRENE-BUTADIENE COPOLYMER AND cis-1,4-POLYISOPRENE CONTAINING FILLERS AND COMPARISON OF THEIR PROPERTIES WITH SULFUR VULCANIZATES[J]. Journal of Radiation Research and Radiation Processing, 1995,13(3):156-160,155.
许云书, 孙颖, H. Siswono, 等. 苯乙烯丁二烯共聚物和顺-1,4-聚异戊二烯的辐射交联以及与用硫磺的交联产物性能的比较[J]. 辐射研究与辐射工艺学报, 1995,13(3):156-160,155. DOI：

Xu Yunshu, Sun Ying, H. Siswono, et al. RADIATION CROSSLINKING OF STYRENE-BUTADIENE COPOLYMER AND cis-1,4-POLYISOPRENE CONTAINING FILLERS AND COMPARISON OF THEIR PROPERTIES WITH SULFUR VULCANIZATES[J]. Journal of Radiation Research and Radiation Processing, 1995,13(3):156-160,155. DOI：

摘要

研究了12种多官能团不饱和单体对SBR（苯乙烯-丁二烯共聚物）和IR（顺-1，4-聚异戊二烯）辐射交联的敏化效应，发现A-TMMT（四丙烯酸四羟甲基甲烷酯）和2G（二甘醇二甲基丙烯酸酯）是SBR和IR的有效敏化剂。对辐射交联SBR和IR的应力-应变、动态力学以及其它性能进行了考察与分析，并与传统硫磺交联法所得产品性能进行了比较，获得了与硫磺交联产物性能相当的辐射交联SBR和IR。

Abstract

The efficiency of 12 kinds of polyfunctional monomers were evaluated for radiation crosslinking of SBR (styrcne-butadiene rubber, polystyrene-co-butadiene) and IR (isoprene rubber, cis-1,4-polyisoprene). It was found A-TMMT(tetramethylolmethane tetraacrylate) and 2 G(diethyleneglycol dimethacrylate) were very effective for SBR and IR respectively in reducing the necessary crosslinking dose. Stress-strain, dynamic mechanical and other properties of radiation crosslinked SBR and IR were analyzed and compared with those obtained through typical sulfur method. The properties of radiation crosslinked SBR and IR are similar to or even better than sulfur crosslinked rubber was concluded.

关键词

苯乙烯-丁二烯共聚物顺-14-聚异戊二烯辐射交联电子束多官能团单体

Keywords

Poly (styrene-co-butadiene)cis-1;4-polyisopreneRadiation crosslinkingPolyfunctional monomerElectron beam

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