甲基丙烯酸三丁基锡酯与甲基丙烯酸甲酯的辐射共聚

赵秉熙; 祝晓红; 穆拉提; 韩哲文

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甲基丙烯酸三丁基锡酯与甲基丙烯酸甲酯的辐射共聚

简讯 | 更新时间：2023-04-26

- 甲基丙烯酸三丁基锡酯与甲基丙烯酸甲酯的辐射共聚
- RADIATION COPOLYMERIZATION OF TRIBUTYLTIN METHACRYLATE AND METHYLMATHACRYLATE
- 辐射研究与辐射工艺学报 1987年5卷第4期页码：24-28
- 作者机构：
  
  1.中国科学技术大学
- 作者简介：
- 基金信息：
  
  中国科学院基金资助的课题
- DOI：
  中图分类号：
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赵秉熙, 祝晓红, 穆拉提, 等. 甲基丙烯酸三丁基锡酯与甲基丙烯酸甲酯的辐射共聚[J]. 辐射研究与辐射工艺学报, 1987,5(4):24-28.

Zhao Benxi, Zhu Xiaohong, Murat, et al. RADIATION COPOLYMERIZATION OF TRIBUTYLTIN METHACRYLATE AND METHYLMATHACRYLATE[J]. Journal of Radiation Research and Radiation Processing, 1987,5(4):24-28.
赵秉熙, 祝晓红, 穆拉提, 等. 甲基丙烯酸三丁基锡酯与甲基丙烯酸甲酯的辐射共聚[J]. 辐射研究与辐射工艺学报, 1987,5(4):24-28. DOI：

Zhao Benxi, Zhu Xiaohong, Murat, et al. RADIATION COPOLYMERIZATION OF TRIBUTYLTIN METHACRYLATE AND METHYLMATHACRYLATE[J]. Journal of Radiation Research and Radiation Processing, 1987,5(4):24-28. DOI：

摘要

甲基丙烯酸三丁基锡酯与甲基丙烯酸甲酯的共聚物是一种优良的自抛光防污漆的基料。我们研究了用,60,Co γ辐射在室温进行合成的新方法，并且对其共聚反应的动力学过程进行了探讨，由反应速率与辐射剂量率的关系R,P,=K,P,I,0.53,，共聚反应中两种单体的竞聚率小于1，以及表观活化能仅为1.29 ×10,4,J/mol，初步确认该共聚反应是自由基反应机制。

Abstract

The copolymer of tributytin methacrylate and methylmethacrylate is a useful self-polishing antifouling paints materials. It was synthesized by radiation polymerization using ,60,Co ,γ, ray at room temperature. It was carried out to study the copolymerization kinetics of the pair of monomers. The relationship between the reaction rate and the dose rate was found to be R,P,=K,P,•I,0.53, and the reactivity ratios were measured to be lass than 1. The overall activition energy was 1.29×10,4,J/mol. It was Supposed that the copolymerization was of radical machanism.

关键词

辐射共聚防污漆聚合反应动力学有机锡聚合物聚合速率

Keywords

Radiation CopolymerizationAntifouling paintspolymerization kinetiesOrganotin polymerPolymerization rate

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甲基丙烯酸三丁基锡酯的辐射聚合