1.中国工程物理研究院核物理与化学研究所 绵阳 621900
钟志京,男,1973年出生,1995年毕业于江西师范大学化学系,1998年于中国工程物理研究院核化学化工专业硕士毕业,现正攻读该专业博士学位
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钟志京, 罗世凯, 傅依备, 等. 127—环氧树脂胶及其组分的辐射效应研究[J]. 辐射研究与辐射工艺学报, 2001,19(2):92-98.
ZHONG Zhijing, LOU Shikai, FU Yibei, et al. THE STUDY OF RADIATION EFFECT ON 127-EPOXY RESIN ADHESIVE AND ITS COMPONENTS[J]. Journal of Radiation Research and Radiation Processing, 2001,19(2):92-98.
研究了在室温条件下,空气、氮气或真空气氛中,γ射线对127—环氧树脂胶及其组分:E-44环氧树脂、邻苯二甲酸二丁酯和无水乙二胺的辐射效应。以气相色谱(GC)法对各种样品,γ,辐解所产生的H,2,、CH,4,和CO,2,等气体产物进行了测定。结果表明,气氛条件和辐射剂量对各种样品辐解生成3种气体产物的量有重要影响。其中CO,2,的生成量不仅直接受气氛中O,2,含量影响,而且与样品分子结构中是否含氧关系密切。127—环氧树脂胶和邻苯二甲酸二丁酯,γ,辐解所生成的H,2,、CH,4,和CO,2,等气体产物的量均随辐射剂量的增大而增大。而且127—环氧树脂胶的,γ,辐解产物H,2,和CH,4,的量以及邻苯二甲酸二丁酯的,γ,辐解产物CH,4,的量均与辐射剂量呈线性递增关系。从辐射化学效应来说,127—环氧树脂的抗辐照性能较差。
127—epoxy resin adhesive and its components: E—44 epoxy resin, dibutyl—o—phthalate and anhydrous ethylenediamine were irradiated with γray in air, nitrogen or vacuum at ambient temperature respectively. The gaseous products such as hydrogen, methane and carbon dioxide were examined by means of GC. Remarkable effect of ambiences and dose on γradiated degradation of these specimen were found. The results indicated that the content of gaseous products increased with dose,but changed with ambiences. The forming of carbon dioxide was not only determined by the amount of oxygen in ambience, but also by whether the specimens struc,¬, ture contained oxygenous groups or not. It was shown that there were good linear increasing relationships between dose and the concentration of gaseou products hydrogen and methane for 127—epoxy resin adhesive, and methane for dibutyl—o—phthalate. All above indicated low radiation—resistance of 127—epoxy resin adhesive.
127—环氧树脂胶γ辐照辐射降解效应
127—Epoxy resin adhesiveγ irradiationRadiation effect
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