冠醚包覆聚苯乙烯磁性颗粒的合成、表征及其对锶离子的吸附性能

孔祥银; 邵宪章; 陈飞; 尹亮亮; 吉艳琴

doi:10.11889/j.1000-3436.2016.rrj.34.020302

您当前的位置：

首页 >

文章列表页 >

冠醚包覆聚苯乙烯磁性颗粒的合成、表征及其对锶离子的吸附性能

更新时间：2021-12-10

- 冠醚包覆聚苯乙烯磁性颗粒的合成、表征及其对锶离子的吸附性能
- Synthesis and characterization of crown-ether-coated poly (styrene/divinylbenzene) magnetic particle and evaluation of its adsorption behavior for strontium (Ⅱ)
- 辐射研究与辐射工艺学报 2016年34卷第2期页码：20302
- 作者机构：
  
  1.中国疾病预防控制中心辐射防护与核安全医学所辐射防护与核应急中国疾病预防控制中心重点实验室北京 100088
  2.China CDC Key Laboratory of Radiological Protection and Nuclear Emergency, National Institute for Radiological Protection, Chinese Center for Disease Control and Prevention, Beijing 100088, China
- 作者简介：
  
  孔祥银,男,1992年1月出生,2013年7月于中国药科大学获得学士学位,现为中国疾病预防控制中心辐射防护与核安全医学所硕士研究生,放射医学专业
  吉艳琴,博士,研究员,E-mail:jiyanqin@nirp.cn
- 基金信息：
- DOI：10.11889/j.1000-3436.2016.rrj.34.020302
  中图分类号：
扫描看全文
孔祥银, 邵宪章, 陈飞, 等. 冠醚包覆聚苯乙烯磁性颗粒的合成、表征及其对锶离子的吸附性能[J]. 辐射研究与辐射工艺学报, 2016,34(2):20302.

Xiangyin KONG, Xianzhang SHAO, Fei CHEN, et al. Synthesis and characterization of crown-ether-coated poly (styrene/divinylbenzene) magnetic particle and evaluation of its adsorption behavior for strontium (Ⅱ)[J]. Journal of Radiation Research and Radiation Processing, 2016,34(2):20302.
孔祥银, 邵宪章, 陈飞, 等. 冠醚包覆聚苯乙烯磁性颗粒的合成、表征及其对锶离子的吸附性能[J]. 辐射研究与辐射工艺学报, 2016,34(2):20302. DOI： 10.11889/j.1000-3436.2016.rrj.34.020302.

Xiangyin KONG, Xianzhang SHAO, Fei CHEN, et al. Synthesis and characterization of crown-ether-coated poly (styrene/divinylbenzene) magnetic particle and evaluation of its adsorption behavior for strontium (Ⅱ)[J]. Journal of Radiation Research and Radiation Processing, 2016,34(2):20302. DOI： 10.11889/j.1000-3436.2016.rrj.34.020302.

摘要

为建立应用磁性颗粒快速分离低水平,90,Sr的方法,分别以沉淀法合成Fe,3,O,4,纳米颗粒,微乳聚合法合成磁性聚苯乙烯-二乙烯苯颗粒(Pst-DVB@Fe,3,O,4,),并将4,4'(5')-二叔丁基二环己基-18-冠-6(DtBuCH18C6)通过物理作用包覆在Pst-DVB@Fe,3,O,4,颗粒表面,最终生成一种新型的核-壳结构的DtBuCH18C6包覆的聚合物磁性颗粒(DtBuCH18C6@Pst-DVB@Fe,3,O,4,)。采用扫描电镜、红外光谱、X射线光电子能谱等方法对颗粒的形貌、结构、表面元素组成及含量进行分析。用于分离水溶液中Sr,2+,的批实验结果表明,Sr,2+,的吸附量随着pH值而增加,而在pH=11和pH=13之间急剧上升,温度升高,其吸附量增加。吸附动力学模型结果表明,Sr,2+,在DtBuCH18C6@Pst-DVB@Fe,3,O,4,表面的吸附更接近于其和Sr,2+,之间形成络合物的单层化学吸附过程,符合Langmuir模型。在优化的条件下其最大吸附容量为2.62 mg/g。

Abstract

To develop a method for rapid separation of low level ,90,Sr using magnetic particles, Fe,3,O,4 ,nanoparticles were prepared by coprecipitation method, and poly (styrene/divinylbenzene) magnetic particles (Pst-DVB@Fe,3,O,4, PF) were synthesized by emulsion polymerization. Finally a new kind of core-shell structure magnetic particle coated with DtBuCH18C6 (DtBuCH18C6@Pst-DVB@Fe,3,O,4, DPF) was developed. The morphology, structure, composition and content of surface elements were analyzed by scanning electron microscope, FT-IR spectroscopy and X-ray photoelectron spectroscopy,etc,. The batch experiment results for the separation of Sr,2+, in aqueous indicated that the adsorption of Sr,2+, to DPF increased with pH value and showed a drastic increase from pH 11 to pH 13. The kinetic model showed that the adsorption of Sr,2+, to DPF was most likely to be a monolayer chemisorption process ,via, forming complexation between DPF and Sr,2+, which was consistent with Langmuir isotherm model. The maximum adsorption capacity of Sr,2+, to DPF was 2.62 mg/g under optional conditions.

关键词

磁性颗粒冠醚锶吸附性能

Keywords

Magnetic particlesCrown etherStrontiumAdsorption behavior

references

朱寿彭 , 李章 . 放射毒理学 , 2004 . :苏州苏州大学出版社 , 268 -269. .

ZHU Shoupeng , LI Zhang . Radiotoxicology , 2004 . :SuzhouSuzhou University Press , 268 -269. .

Inan S , Nostar E . Structure and ion exchange behavior of zirconium antimonates for strontium . Separation Science and Technology , 2013 . 48 (9 ):1364 -1369. .

Horwitz E , Dietz M , Fisher D . Extraction of strontium from nitric acid solutions using dicyclohexano-18-crown-5 and its derivatives . Solvent Extraction and Ion Exchange , 1990 . 8 (4-5 ):557 -572. .

Vaňura P , Jedináková-Křížová V , Yoshioka A . Extraction separation of strontium and yttrium radionuclides by hydrogen heptachlorodicarbollylcobaltate in the presence of benzo-15-crown-5 . Journal of Radioanalytical and Nuclear Chemistry , 2002 . 251 (3 ):511 -514. .

Vajda N , Kim C K . Determination of radiostrontium isotopes: a review of analytical methodology . Applied Radiation and Isotopes , 2010 . 68 (12 ):2306 -2326. .

Schulz W W , Bray L A . Solvent extraction recovery of byproduct 137Cs and 90Sr from HNO3 solutions-a technology review and assessment . Separation Science and Technology , 1987 . 22 (2-3 ):191 -214. .

Zhang A , Wei Y Z , Kumagai M , 等 . Kinetics of the adsorption of strontium (Ⅱ) by a novel silica-based 4,4',(5')-di(tert-butylcyclohexano)-18-crown-6 extraction resin in nitric acid medium . Journal of Radioanalytical and Nuclear Chemistry , 2004 . 262 (3 ):739 -744. .

Horwitz E P , Dietz M L , Fisher D E . SREX: a new process for the extraction and recovery of strontium from acidic nuclear waste streams . Solvent Extraction and Ion Exchange , 1991 . 9 (1 ):1 -25. .

Horwitz E P , Chiarizia R , Dietz M L . Novel strontium-selective extraction chromatographic resin . Solvent Extraction and Ion Exchange , 1992 . 10 (2 ):313 -336. .

Heilgeist M . Use of extraction chromatography, ion chromatography and liquid scintillation spectrometry for rapid determination of strontium-89 and strontium-90 in food in cases of increased release of radionuclides . Journal of Radioanalytical and Nuclear Chemistry , 2000 . 245 (2 ):249 -254. .

党磊 , 吉艳琴 . 低水平~(90)Sr的分析方法研究进展 . 核化学与放射化学 , 2010 . 32 (3 ):129 -144. .

DANG Lei , JI Yanqin . Advance of methodology for determination of low level strontium-90 . Journal of Nuclear and Radiochemistry , 2010 . 32 (3 ):129 -144. .

Wu W , He Q , Jiang C . Magnetic iron oxide nanoparticles: synthesis and surface functionalization strategies . Nanoscale Research Letters , 2008 . 3 (11 ):397 -415. .

Maninder K , Huijin Z , Leigh M , 等 . Conjugates of magnetic nanoparticle-actinide specific chelator for radioactive waste separation . Environmental Science and Technology , 2013 . 47 (21 ):11942 -11959. .

Ranjeet K , Abshar H , Nusrat I , 等 . Synthesis and surface engineering of magnetic nanoparticles for environmental cleanup and pesticide residue analysis: a review . Journal of Separation Science , 2014 . 37 (14 ):1805 -1825. .

Kaminski M D , Nunez L , Visser A E . Evaluation of extractant-coated ferromagnetic microparticles for the recovery of hazardous metals from waste solution . Separation Science and Technology , 1999 . 34 (6 ):1103 -1120. .

Nuñez L . Waste remediation using in situ magnetically assisted chemical separation . Separation Science and Technology , 1993 . 30 (30 ):1455 -1471. .

Nuñez L , Buchholz B A , Kaminski M , 等 . Actinide separation of high-level waste using solvent extractants on magnetic microparticles . Separation Science and Technology , 1996 . 31 (10 ):1393 -1407. .

Shaibu B S , Reddy M L P , Bhattacharyya A , 等 . Evaluation of Cyanex 923-coated magnetic particles for the extraction and separation of lanthanides and actinides from nuclear waste streams . Journal of Magnetism and Magnetic Materials , 2006 . 301 (2 ):312 -318. .

Horwitz E P , Dietz M , Fisher D . Correlation of the extraction of strontium nitrate by a crown ether with the water content of the organic phase . Solvent Extraction and Ion Exchange , 1990 . 8 (1 ):199 -208. .

Zhang A , Xiao C , Liu Y , 等 . Preparation of macroporous silica-based crown ether materials for strontium separation . Journal of Porous Materials , 2010 . 17 (2 ):153 -161. .

Yi R , Ye G , Wu F , 等 . Magnetic solid-phase extraction of strontium using core-shell structured magnetic microspheres impregnated with crown ether receptors: a response surface optimization . Journal of Radioanalytical and Nuclear Chemistry , 2015 . 1 -10. .

Shaikh Y , Lai E , Sadi B , 等 . Magnetic nanoparticles impregnated with 18-crown-6 ether: hybrid material synthesis for binding and detection of radioactive strontium . Nanoscience Technology , 2015 . 2 (1 ):1 -5. .

Wang H , Shao X Z , Tian Q , 等 . Synthesis of TBP-coated magnetic Pst-DVB particles for uranium separation . Nuclear Science and Techniques , 2014 . 25 (3 ):22 -26. .

吉艳琴, 李金英, 苏旭. 一种磁性颗粒萃取剂及分离放射性核素的方法: 中国, CN101231899[P]. 2008-02-30.

JI Yanqin, LI Jinying, SU Xu. A extractant and a method for separating radioactive isotope using magnetic particles, China, CN101231899[P]. 2008-02-30.

Hrdina A , Lai E , Li C , 等 . Preliminary studies of an 18-crown-6 ether modified magnetic cation exchange polymer in rapid 90Sr bioassay . Health Physics , 2011 . 101 (2 ):187 -195. .

Tartaj P , Morales M D P , Veintemillasverdaguer S , 等 . The preparation of magnetic nanoparticles for applications in biomedicine . Journal of Physics D Applied Physics , 2003 . 36 (36): .

黄惠忠 . 表面化学分析 , 2007 . :上海华东理工大学出版社 , 271 -280. .

HUANG Huizhong . Surface chemical analysis , 2007 . :ShanghaiEast China University of Science and Technology Press , 271 -280. .

Carroll S A , Roberts S K , Criscenti L J , 等 . Surface complexation model for strontium sorption to amorphous silica and goethite . Geochemical Transactions , 2008 . 9 (1 ):1 -26. .

Ngomsik A F , Bee A , Siaugue J M , 等 . Co(Ⅱ) removal by magnetic alginate beads containing Cyanex 272® . Journal of Hazardous Materials , 2009 . 166 (2-3 ):1043 -1049. .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据