微波非热效应对有机硫化合物结构的影响

马祥梅; 张明旭; 闵凡飞; 王斌

doi:10.11889/j.1000-3436.2016.rrj.34.030304

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微波非热效应对有机硫化合物结构的影响

辐射化学 | 更新时间：2021-12-10

- 微波非热效应对有机硫化合物结构的影响
- Influence of the non-thermal effect of microwaves on organic sulfur compounds structure
- 辐射研究与辐射工艺学报 2016年34卷第3期页码：46-52
- 作者机构：
  
  1.安徽理工大学化工学院淮南 232001
  2.安徽理工大学材料工程学院淮南 232001
- 作者简介：
  
  [ "马祥梅,女,1971年9月出生,2015年于安徽理工大学获博士学位,研究方向为洁净煤技术,副教授,E-mail:wb6314005@126.com", "Ph.D. MA Xiangmei (female) was born in September 1971 and received her doctoral degree from Anhui University of Science & Technology in 2015, focusing on clean coal technology, associate professor, E-mail: wb6314005@126.com" ]
  王斌,副教授,E-mail:wbmxmwzc@126.comWANG Bin, associate professor, E-mail: wbmxmwzc@126.com
- 基金信息：
  
  国家重点基础研究发展计划(2012CB214901);安徽省教育厅自然科学研究重点项目(KJ2016A196);安徽理工大学博士基金资助(11110)
- DOI：10.11889/j.1000-3436.2016.rrj.34.030304
  中图分类号：
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马祥梅, 张明旭, 闵凡飞, 等. 微波非热效应对有机硫化合物结构的影响[J]. 辐射研究与辐射工艺学报, 2016,34(3):46-52.

Xiangmei MA, Mingxu ZHANG, Fanfei MIN, et al. Influence of the non-thermal effect of microwaves on organic sulfur compounds structure[J]. Journal of Radiation Research and Radiation Proces, 2016,34(3):46-52.
马祥梅, 张明旭, 闵凡飞, 等. 微波非热效应对有机硫化合物结构的影响[J]. 辐射研究与辐射工艺学报, 2016,34(3):46-52. DOI： 10.11889/j.1000-3436.2016.rrj.34.030304.

Xiangmei MA, Mingxu ZHANG, Fanfei MIN, et al. Influence of the non-thermal effect of microwaves on organic sulfur compounds structure[J]. Journal of Radiation Research and Radiation Proces, 2016,34(3):46-52. DOI： 10.11889/j.1000-3436.2016.rrj.34.030304.

摘要

为探究微波辐照脱除煤中有机硫的作用机理以及影响程度,通过核磁共振氢谱、红外光谱和激光共聚焦显微拉曼光谱技术,研究了微波非热效应对有机硫模型化合物结构性能的影响。红外光谱测试说明,微波辐照有机硫化合物存在非热效应并影响化学键的键能分布、基团的振动强度和稳定性,但仅限于分子的极化机制,不会破坏分子中原有的化学键也不会生成新的化学键和基团;核磁共振氢谱揭示非热效应影响了模型化合物分子内部的电子云密度分布和磁环境,对含硫化合物产生的双重极化作用既可改变微观的电子或原子极化,也可改变分子固有偶极矩的取向;显微激光拉曼光谱证明非热效应可有效极化含硫键,使之振动强度减弱,从而有助于有机硫的微波辐射脱除。

Abstract

In order to explore the mechanism of action and impact degree of removing organic sulfur from coal by microwave irradiation, the proton nuclear magnetic resonance spectroscopy (,1,HNMR), Fourier transform infrared spectroscopy (FT-IR) and Raman laser confocal spectroscopy (RLCS) techniques were used to investigate the effect of microwave non-thermal on the structural and performance of the model organic sulfur compounds. The FT-IR results showed that the non-thermal effects really existed and could affect the bond energy distribution, vibration strength and stability of the groups, but only on the molecular mechanisms of polarization of organic sulfur compound, not destroyed any original molecule chemical bond or generated new chemical bonds and groups. ,1,HNMR revealed that the non-thermal effect influenced the electron density distribution and magnetic environment inside the model compound molecular. The dual polarization characteristics of sulfur compounds changed not only the microscopic electron polarization or atomic polarization, but also the orientation of permanent dipole moment. Raman proved that the microwave non-thermal effect could effectively polarize the sulfur-containing chemical bonds, which weakened the vibration intensity, and thus contributed to the remove of organic sulfur from coal.

关键词

硫醇/醚类微波辐射非热效应分子结构

Keywords

Thiols/thioethersMicrowave radiationNon-thermal effectMolecular structure

references

付必伟 , 艾志久 , 胡坤 , 等 . 微波辐射稠油降粘脱水实验研究 . 辐射研究与辐射工艺学报 , 2015 . 33 (3 ):030401 DOI:10.11889/j.1000-3436.2015.rrj.33.030401http://doi.org/10.11889/j.1000-3436.2015.rrj.33.030401 .

Biwei FU , Zhijiu AI , Kun HU , 等 . Experimental research on microwave demulsification and dehydration of heavy oil . Journal of Radiation Research and Radiation Processing , 2015 . 33 (3 ):030401 DOI:10.11889/j.1000-3436.2015.rrj.33.030401http://doi.org/10.11889/j.1000-3436.2015.rrj.33.030401 .

雷佳莉 , 周敏 , 严东 , 等 . 煤炭微波脱硫技术研究进展 . 化工生产与技术 , 2012 . 19 (1 ):43 -46 . DOI:10.3969/j.issn.1006-6829.2012.01.014http://doi.org/10.3969/j.issn.1006-6829.2012.01.014 .

Jiali LEI , Min ZHOU , Dong YAN , 等 . Research progress of desulfurization from coal with microwave technology . Chemical Production and Technology , 2012 . 19 (1 ):43 -46 . DOI:10.3969/j.issn.1006-6829.2012.01.014http://doi.org/10.3969/j.issn.1006-6829.2012.01.014 .

M Shimon . Mechanisms of objectionable textural changes by microwave reheating of foods:a review . Journal of Food Science , 2012 . 77 (1 ):57 -62 . DOI:10.1111/j.1750-3841.2011.02515.xhttp://doi.org/10.1111/j.1750-3841.2011.02515.x .

T Santos , M A Valente , J Monteiro , 等 . Electromagnetic and thermal history during microwave heating . Applied Thermal Engineering , 2011 . 31 (16 ):3255 -3261 . DOI:10.1016/j.applthermaleng.2011.06.006http://doi.org/10.1016/j.applthermaleng.2011.06.006 .

P Jin , G He , D Q Xiao , 等 . Microstructure, optical, electrical properties, and leakage current transport mechanism of sol-gel-processed high-k HfO2 gate dielectrics . Ceramics International , 2016 . 142 6761 -6769 . DOI:10.1016/j.ceramint.2016.01.050http://doi.org/10.1016/j.ceramint.2016.01.050 .

C A Pickles , F Gao , S Kelebek . Microwave drying of a low-rank sub-bituminous coal . Minerals Engineering , 2014 . 62 31 -42 . DOI:10.1016/j.mineng.2013.10.011http://doi.org/10.1016/j.mineng.2013.10.011 .

X M Ma , M X Zhang , F F Min , 等 . Fundamental study on removal of organic sulfur from coal by microwave irradiation . International Journal of Mineral Processing , 2015 . 139 31 -35. .

肖海平 , 周俊虎 , 刘建忠 , 等 . 有机钙高温脱硫特性 . 环境科学 , 2007 . 28 (8 ):1861 -1865 . DOI:10.3321/j.issn:0250-3301.2007.08.037http://doi.org/10.3321/j.issn:0250-3301.2007.08.037 .

Haiping XIAO , Junhu ZHOU , Jianzhong LIU , 等 . Desulfurization characteristic of organic calcium at high temperature . Environmental Science , 2007 . 28 (8 ):1861 -1865 . DOI:10.3321/j.issn:0250-3301.2007.08.037http://doi.org/10.3321/j.issn:0250-3301.2007.08.037 .

魏砾宏 , 姜秀民 , 李爱民 . 矿物成分对超细化煤粉燃烧硫转化影响的实验研究 . 环境科学 , 2006 . 27 (9 ):1722 -1726 . DOI:10.3321/j.issn:0253-2468.2006.11.005http://doi.org/10.3321/j.issn:0253-2468.2006.11.005 .

Lihong WEI , Xiumin JIANG , Aimin LI . Influence of mineral matter on sulfur conversion in coal during combustion . Environmental Science , 2006 . 27 (9 ):1722 -1726 . DOI:10.3321/j.issn:0253-2468.2006.11.005http://doi.org/10.3321/j.issn:0253-2468.2006.11.005 .

J Cheng , J H Zhou , Y C Li , 等 . Improvement of coal water slurry property through coal physicochemical modifications by microwave irradiation and thermal heat . Energy & Fuels , 2008 . 22 2422 -2428 . DOI:10.1021/ef7005244http://doi.org/10.1021/ef7005244 .

Hoz A Dela , Á Díaz-Ortiz , A Moreno . Microwaves in organic synthesis. Thermal and non-thermal microwave effects . Chemical Society Reviews , 2005 . 34 (2 ):164 -178 . DOI:10.1002/chin.200521275http://doi.org/10.1002/chin.200521275 .

谢柳娟. 深层烃源高演化阶段生气潜力与机理研究[D]. 杭州. 浙江大学. 2014.

XIE Liujuan. The gas generation potential and processes of high mature hydrocarbon source in deep basin[D]. Hangzhou. Zhejiang University. 2014.

王传贵 , 陈美玲 , 张双燕 , 等 . 伽玛射线辐照接枝对杨树木材力学性能的影响 . 辐射研究与辐射工艺学报 , 2013 . 31 (6 ):060401 .

Chuangui WANG , Meiling CHEN , Shuangyan ZHANG , 等 . Effects of gamma-ray irradiation graft on mechanical properties of polar wood . Journal of Radiation Research and Radiation Processing , 2013 . 31 (6 ):060401 .

M Scpliarsky , A Asthagiri , S R Phillpor , 等 . Atomic level simulation of ferrocleetrieity in oxide materials . Current Opinion in Solid State & Materials Science , 2005 . 9 (3 ):107 -113 . DOI:10.1016/j.cossms.2006.05.002http://doi.org/10.1016/j.cossms.2006.05.002 .

A Loupy , F Maurel , A Sabatié-Gogová . Improvements in Diels-Alder cycloadditions with some acetylenic compounds under solvent-free microwave-assisted conditions:experimental results and theoretical approaches . Tetrahedron , 2004 . 60 (7 ):1683 -1691 . DOI:10.1016/j.tet.2003.11.042http://doi.org/10.1016/j.tet.2003.11.042 .

季瑗 , 周群 , 李晓伟 , 等 . 对巯基苯甲酸的表面增强拉曼光谱 . 分析化学 , 2004 . 32 (8 ):1050 -1052 . DOI:10.3321/j.issn:0253-3820.2004.08.017http://doi.org/10.3321/j.issn:0253-3820.2004.08.017 .

Yuan JI , Qun ZHOU , Xiaowei LI , 等 . Surface enhanced Raman spectroscopy of 4-mercaptobenzoic acid . Chinese Journal of Analytical Chemistry , 2004 . 32 (8 ):1050 -1052 . DOI:10.3321/j.issn:0253-3820.2004.08.017http://doi.org/10.3321/j.issn:0253-3820.2004.08.017 .

张志义 , 许以明 . 光卟啉(YHPD)光敏作用的分子机制-YHPD 对蛋白质微观光敏损伤的激光拉曼光谱研究 . 中国科学(B) , 1991 . 6 595 -601 . DOI:10.1360/zb1991-21-6-595http://doi.org/10.1360/zb1991-21-6-595 .

Zhiyi ZHANG , Yiming XU . Raman spactroscopyic study on molecular mechanism of YHPD photosensitization in microcosmic and photosensitive damage of protein . Science China (B) , 1991 . 6 595 -601 . DOI:10.1360/zb1991-21-6-595http://doi.org/10.1360/zb1991-21-6-595 .

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