1.江南大学纺织服装学院无锡 214122
2.江苏红豆实业股份有限公司无锡 214199
3.川庆钻探蜀渝公司成都 610000
[ "陈诚, 男, 1988年11月出生, 2016年6月毕业于新疆大学, 现为江南大学纺织服装学院博士研究生, 纺织科学与工程专业, 主要从事辐射技术在纺织品染整加工中的应用研究, E-mail:450548205@qq.com", "CHEN Cheng (male) was born in November 1988, and graduated from Xinjiang University in June 2016. Now he is adoctor candidate in College of Textile and Clothing, Jiangnan University, majoring in textile science and engineering on application ofradiation technology on textiles dyeing and finishing. E-mail:450548205@qq.com" ]
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陈诚, 闫文君, 陈川生, 等. 联用紫外线辐射改性的羊毛织物茶色素同浴媒染工艺[J]. 辐射研究与辐射工艺学报, 2017,35(1):10303.
Cheng CHEN, Wenjun YAN, Chuansheng CHEN, et al. Tea pigment dyeing process with mordant of wool fabric treated by ultraviolet radiation[J]. Journal of Radiation Research and Radiation Processing, 2017,35(1):10303.
陈诚, 闫文君, 陈川生, 等. 联用紫外线辐射改性的羊毛织物茶色素同浴媒染工艺[J]. 辐射研究与辐射工艺学报, 2017,35(1):10303. DOI: 10.11889/j.1000-3436.2017.rrj.35.010303.
Cheng CHEN, Wenjun YAN, Chuansheng CHEN, et al. Tea pigment dyeing process with mordant of wool fabric treated by ultraviolet radiation[J]. Journal of Radiation Research and Radiation Processing, 2017,35(1):10303. DOI: 10.11889/j.1000-3436.2017.rrj.35.010303.
以茶色素/金属媒染剂同浴媒染法为基础,对分别应用不同金属媒染剂的羊毛织物茶色素同浴媒染工艺进行筛选,对比经紫外线辐射改性前后的羊毛织物染色性能。结果表明,茶色素/铜媒同浴媒染的改性前后羊毛织物,K/S,值与固色率均较其余工艺高,并通过对比实验数据证实紫外线辐射有利于提升羊毛织物染色性能,故将其与茶色素/铜媒同浴媒染工艺联用进而增强茶色素染色效果。通过单因素分析对联用紫外线辐射改性的羊毛织物茶色素/铜媒同浴媒染工艺进行讨论并选择紫外线辐射改性时间、铜媒用量及染色时间等因子的优化范围,进而利用3因子二次通用旋转组合设计进行优化,从而确定优化工艺为(用量/对织物重(o.w.f)):紫外线辐射改性9 min,茶色素5.0%,铜媒1.7%,HCOOH 2.0%,pH=3.5~4.0,浴比1:50,95℃条件下染色60 min。与常规茶色素后铬媒染工艺相比,该优化工艺具有更好的染色效果和较低的金属媒染剂用量。
Based on tea pigment dyeing process with mordant of wool fabric, screening of the dyeing processes with different metal mordants were carried out, and dyeing properties of wool fabric before and after ultraviolet radiation were compared. The results showed that ,K/S, value and dye fixation of wool fabric dyed by tea pigment dyeing process with CuSO,4, were higher than that in other processes, and improving dyeing properties of wool fabric treated by ultraviolet radiation was confirmed according to the comparison of experimental data. Therefore, the ultraviolet radiation was combined with tea pigment dyeing process with CuSO,4, to improve the tea pigment dyeing effects of wool fabric. The tea pigment dyeing process with CuSO,4, of wool fabric treated by ultraviolet radiation was discussed during single factor analysis, these optimized scopes of ultraviolet radiation time, CuSO,4, content and dyeing time were selected, then the process was optimized by using the three-factor quadratic general rotary unitized design. The optimum process was determined as follows (dosage/on weight of fabric (o.w.f)):ultraviolet radiation time 9 min, tea pigment 5.0%, CuSO,4, 1.7%, HCOOH 2.0%, pH=3.5~4.0, 95℃, dyeing time 60 min, bath ratio 1:50. Compared with conventional tea pigment after chrome process, the dyeing effects of wool fabric dyed by the optimum process, which possessed of lower metal mordant content, were better.
紫外线辐射羊毛织物茶色素金属媒染剂同浴媒染工艺优化
Ultraviolet radiationWool fabricTea pigmentMetal mordantDyeing process with mordantOptimization
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