γ射线辐照改善PBAT增韧的麦秸粉/PBS复合材料性能

杨明成; 张振亚; 张宏娜; 张本尚; 田青亮; 刘树博; 陈超

doi:10.11889/j.1000-3436.2017.rrj.35.060302

您当前的位置：

首页 >

文章列表页 >

γ射线辐照改善PBAT增韧的麦秸粉/PBS复合材料性能

辐射化学 | 更新时间：2021-12-10

- γ射线辐照改善PBAT增韧的麦秸粉/PBS复合材料性能
- Improving properties of wheat straw powder/poly (butylene succinate) composites toughened with poly (butylene adipate-co-terephthalate) by γ-ray irradiation
- 辐射研究与辐射工艺学报 2017年35卷第6期
- 作者机构：
  
  1.河南省科学院同位素研究所有限责任公司郑州 450015
- 作者简介：
  
  [ "杨明成, 男, 1973年出生, 2008年于郑州大学获博士学位, 研究员, 主要从事核技术应用研究, E-mail:ymch-7305@126.com", "YANG Mingcheng (male) was born in 1973, and received his banchelor's degree from Zhengzhou University. Now he is a professor egageing in nuclear technicle. E-mail:ymch-7305@126.com" ]
- 基金信息：
  
  河南省重点科技攻关项目(152102210163)
- DOI：10.11889/j.1000-3436.2017.rrj.35.060302
  中图分类号：
扫描看全文
杨明成, 张振亚, 张宏娜, 等. γ射线辐照改善PBAT增韧的麦秸粉/PBS复合材料性能[J]. 辐射研究与辐射工艺学报, 2017,35(6):060302-6.

Mingcheng YANG, Zhenya ZHANG, Hongna ZHANG, et al. Improving properties of wheat straw powder/poly (butylene succinate) composites toughened with poly (butylene adipate-co-terephthalate) by γ-ray irradiation[J]. Journal of Radiation Research and Radiation Processing, 2017,35(6):060302-6.
杨明成, 张振亚, 张宏娜, 等. γ射线辐照改善PBAT增韧的麦秸粉/PBS复合材料性能[J]. 辐射研究与辐射工艺学报, 2017,35(6):060302-6. DOI： 10.11889/j.1000-3436.2017.rrj.35.060302.

Mingcheng YANG, Zhenya ZHANG, Hongna ZHANG, et al. Improving properties of wheat straw powder/poly (butylene succinate) composites toughened with poly (butylene adipate-co-terephthalate) by γ-ray irradiation[J]. Journal of Radiation Research and Radiation Processing, 2017,35(6):060302-6. DOI： 10.11889/j.1000-3436.2017.rrj.35.060302.

摘要

以聚己二酸-对苯二甲酸丁二醇酯（Poly（butylene adipate-co-terephthalate），PBAT）为增韧材料，利用熔融共混复合技术，制备了生物可降解的麦秸粉/聚对苯二甲酸丁二醇酯（Poly（butylene succinate），PBS）-PBAT复合材料，并对其进行辐照交联。考察PBAT质量分数和,60,Co γ射线辐照不同吸收剂量对麦秸粉/PBS-PBAT复合材料的热学性能、力学性能和凝胶量的影响。结果表明：当PBAT的质量分数为30%时，麦秸粉/PBS-PBAT复合材料的冲击强度提高了13%；随吸收剂量的增大，麦秸粉/PBS-PBAT复合材料的力学性能和凝胶含量均得到了提高。麦秸粉/PBS-PBAT复合材料经,60,Co γ射线辐照后，完全热分解温度达到550℃，提高了约50℃。

Abstract

The biodegradable wheat straw powder/PBS[poly (butylene succinate)]-PBAT[poly (butylene adipate-co-terephthalate)], composites were prepared by melt-blending, wherein PBAT served as the toughening material. The composites were then subjected to γ-ray irradiation. The effects of PBAT content and different absorbed doses of ,60,Co γ-ray irradiation on the thermal properties, mechanical properties, and gel content of the wheat straw powder/PBS-PBAT composites were studied. The results showed that the impact strength of the composite increased by 13% when the mass fraction of PBAT was 30%. The mechanical properties and gel content of wheat straw powder/PBS-PBAT improved with increasing absorbed doses. The complete thermal decomposition temperature of the wheat straw powder/PBS-PBAT composite irradiated by ,60,Co γ-rays was 550℃, which increased by 50℃ or so.

关键词

麦秸粉/PBS-PBAT吸收剂量力学性能凝胶热分解

Keywords

Wheat straw powder/PBS-PBAT compositesAbsorbed doseMechanical propertiesGel contentThermal decomposition

references

L F Liu , J Y Yu , L D Chen , 等 . Mechanical properties of Poly (butylene succinate)(PBS) biocomposites reinforced with surface modified jute fiber . Composites:part A , 2009 . 40 (3 ):669 -674 . DOI:10.1016/j.compositesa.2009.03.002http://doi.org/10.1016/j.compositesa.2009.03.002 .

曾维 , 李梦影 , 甄智勇 , 等 . EEA与E-BA-GMA的复配对PLA性能与结构的影响 . 塑料工业 , 2016 . 40 (8 ):76 -79 . DOI:10.3969/j.issn.1005-5770.2016.08.018http://doi.org/10.3969/j.issn.1005-5770.2016.08.018 .

Wei ZENG , Mengying LI , Zhiyong ZHEN , 等 . Effects of EEA and E-BA-GMA compound on properties and microstructure of PLA . China Plastics Industry , 2016 . 40 (8 ):76 -79 . DOI:10.3969/j.issn.1005-5770.2016.08.018http://doi.org/10.3969/j.issn.1005-5770.2016.08.018 .

廖才智 . 生物降解性塑料PBS的研究进展 . 塑料科技 , 2010 . 7 (38 ):93 -97 . DOI:10.15925/j.cnki.issn1005-3360.2010.07.016http://doi.org/10.15925/j.cnki.issn1005-3360.2010.07.016 .

Caizhi LIAO . Research progress of biodegradable plastic PBS . Plastics Technology , 2010 . 7 (38 ):93 -97 . DOI:10.15925/j.cnki.issn1005-3360.2010.07.016http://doi.org/10.15925/j.cnki.issn1005-3360.2010.07.016 .

F Harnnecker , Rosa Derval dos Santos , D M Lenz . Biodegradable polyester-based blend reinforced with curaua fiber:thermal, mechanical and biodegradation behaviour . Journal of Polymers and the Environment , 2012 . 20 (1 ):237 -244 . DOI:10.1007/s10924-011-0382-5http://doi.org/10.1007/s10924-011-0382-5 .

L Conzatti , F Giunco , P Stagnaro , 等 . Polyester-based biocomposites containing wool fibers . Composites:part A , 2012 . 43 (7 ):1113 -1119 . DOI:10.1016/j.compositesa.2012.02.019http://doi.org/10.1016/j.compositesa.2012.02.019 .

宁平 , 甘典松 , 肖运鹤 . PBAT/PVB共混物相容性及性能的研究 . 合成材料老化与应用 , 2010 . 39 (2 ):12 -17 . DOI:10.16584/j.cnki.issn1671-5381.2010.02.003http://doi.org/10.16584/j.cnki.issn1671-5381.2010.02.003 .

Ping NING , Diansong GAN , Yunhe XIAO . Study of PBAT/PVB blends miscibility and properties . Synthetic Materials Aging and Application , 2010 . 39 (2 ):12 -17 . DOI:10.16584/j.cnki.issn1671-5381.2010.02.003http://doi.org/10.16584/j.cnki.issn1671-5381.2010.02.003 .

王秋艳 , 许国志 , 翁云宣 . PPC/PBAT生物降解材料热性能和力学性能的研究 . 塑料科技 , 2011 . 39 (6 ):51 -54 . DOI:10.15925/j.cnki.issn1005-3360.2011.06.017http://doi.org/10.15925/j.cnki.issn1005-3360.2011.06.017 .

Qiuyan WANG , Guozhi XU , Yunxuan WENG . Research on thermal and mechanical properties of PPC/PBAT biodegradable materials . Plastics Technology , 2011 . 39 (6 ):51 -54 . DOI:10.15925/j.cnki.issn1005-3360.2011.06.017http://doi.org/10.15925/j.cnki.issn1005-3360.2011.06.017 .

吕怀兴 , 杨彪 , 许国志 . PBS/PBAT共混型全生物降解材料的制备及性能研究 . 中国塑料 , 2009 . 23 (8 ):18 -21 . DOI:10.19491/j.issn.1001-9278.2009.08.004http://doi.org/10.19491/j.issn.1001-9278.2009.08.004 .

Huaixing LYU , Biao YANG , Guozhi XU . Preparation and properties of fully biodegradable poly (butylene succinate)/poly (butylene adipate terephthalate) blends . China Plastics , 2009 . 23 (8 ):18 -21 . DOI:10.19491/j.issn.1001-9278.2009.08.004http://doi.org/10.19491/j.issn.1001-9278.2009.08.004 .

刘浩 , 韩常玉 , 董丽松 . 聚丁二酸丁二醇酯的强化辐射交联 . 河南大学学报(自然科学版) , 2009 . 39 (4 ):365 -369 . DOI:10.15991/j.cnki.411100.2009.04.011http://doi.org/10.15991/j.cnki.411100.2009.04.011 .

Hao LIU , Changyu HAN , Lisong DONG . Study on the radiation cross-linking of poly (butylene succinate) . Journal of Henan University (Natural Science) , 2009 . 39 (4 ):365 -369 . DOI:10.15991/j.cnki.411100.2009.04.011http://doi.org/10.15991/j.cnki.411100.2009.04.011 .

刘亚丽 , 揣成智 . PBAT增韧改性交联PBS的性能研究 . 塑料工业 , 2014 . 42 (11 ):30 -33 . DOI:10.3969/j.issn.1005-5770.2014.11.008http://doi.org/10.3969/j.issn.1005-5770.2014.11.008 .

Yali LIU , Chengzhi CHUAI . Research on properties of PBAT toughening and modifying crosslinked PBS . China Plastics Industry , 2014 . 42 (11 ):30 -33 . DOI:10.3969/j.issn.1005-5770.2014.11.008http://doi.org/10.3969/j.issn.1005-5770.2014.11.008 .

宋剑斌 , 袁全平 , 黄彪 , 等 . 适宜共混速度改善低密度聚乙烯/竹粉复合材料力学与流变性能 . 农业工程学报 , 2015 . 31 (13 ):309 -314 . DOI:10.11975/j.issn.1002-6819.2015.13.043http://doi.org/10.11975/j.issn.1002-6819.2015.13.043 .

Jianbin SONG , Quanping YUAN , Biao HUANG , 等 . Proper blending rate improving mechanical and rheological properties of low density polyethylene/bamboo powder composites . Transactions of the Chinese Society of Agricultural Engineering , 2015 . 31 (13 ):309 -314 . DOI:10.11975/j.issn.1002-6819.2015.13.043http://doi.org/10.11975/j.issn.1002-6819.2015.13.043 .

王勋林 , 吴胜先 . PPC/PBAT共混复合材料性能的研究 . 塑料科技 , 2012 . 40 (10 ):70 -73 . DOI:10.15925/j.cnki.issn1005-3360.2012.10.017http://doi.org/10.15925/j.cnki.issn1005-3360.2012.10.017 .

Xunlin WANG , Shengxian WU . Study on the properties of PPC/PBAT blends composite . Plastics Technology , 2012 . 40 (10 ):70 -73 . DOI:10.15925/j.cnki.issn1005-3360.2012.10.017http://doi.org/10.15925/j.cnki.issn1005-3360.2012.10.017 .

刘艳玲 , 孙希静 , 李娟娟 , 等 . 超声挤出制备聚对苯二甲酸乙二醇酯/膨胀石墨复合材料及其结晶和分散形态 . 四川师范大学学报(自然科学版) , 2017 . 40 (3 ):347 -351 . DOI:10.3969/j.issn.1001-8395.2017.03.013http://doi.org/10.3969/j.issn.1001-8395.2017.03.013 .

Yanling LIU , Xijing SUN , Juanjuan LI , 等 . Ultrasonic oscillation induced morphology and property development of polyethylene terephthalate/expended graphite composites . Journal of Sichuan Normal University (Natural Science) , 2017 . 40 (3 ):347 -351 . DOI:10.3969/j.issn.1001-8395.2017.03.013http://doi.org/10.3969/j.issn.1001-8395.2017.03.013 .

Z Gan , K Kuwabara , M Yamamoto , 等 . Solid-state structures and thermal properties of aliphatic-aromatic poly (butylene adipate-co-butylene terephthalate) copolyesters . Polymer Degradation and Stability , 2004 . 83 (2 ):289 -300 . DOI:10.1016/S0141-3910(03)00274-Xhttp://doi.org/10.1016/S0141-3910(03)00274-X .

Y Someya , N Kondo , M Shibata . Biodegradation of poly (butylene adipate-co-butylene terephthalate)/layeredsilicate nanocomposites . Journal of Applied Polymer Science , 2007 . 106 (2 ):730 -736 . DOI:10.1002/app.24174http://doi.org/10.1002/app.24174 .

杨明成 , 罗永全 , 朱军 , 等 . γ射线辐射对秸秆粉/PBS复合材料性能的影响 . 核技术 , 2013 . 36 (11 ):30 -36 . DOI:10.11889/j.0253-3219.2013.hjs.36.110206http://doi.org/10.11889/j.0253-3219.2013.hjs.36.110206 .

Mingcheng YANG , Yongquan LUO , Jun ZHU , 等 . γ-ray radiation effect on properties of straw powder/PBS composite . Nuclear Techniques , 2013 . 36 (11 ):30 -36 . DOI:10.11889/j.0253-3219.2013.hjs.36.110206http://doi.org/10.11889/j.0253-3219.2013.hjs.36.110206 .

张贞浴 , 秦川江 , 张艳红 , 等 . 生物可降解聚丁二酸丁二醇酯的合成及扩链改性 . 黑龙江大学自然科学学报 , 2005 . 22 (5 ):642 -644 . DOI:10.13482/j.issn1001-7011.2005.05.014http://doi.org/10.13482/j.issn1001-7011.2005.05.014 .

Zhenyu ZHANG , Chuanjiang QIN , Yanhong ZHANG , 等 . Synthesis of biodegradability poly (butylene succinate) and modification by copolymerizing . Journal of Natural Science of Heilongjiang University , 2015 . 22 (5 ):642 -644 . DOI:10.13482/j.issn1001-7011.2005.05.014http://doi.org/10.13482/j.issn1001-7011.2005.05.014 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

甲基丙烯酸缩水甘油酯改性氮化硼纳米片掺杂环氧树脂及其耐辐射性能

双酚A型环氧树脂的1.5 MeV电子束辐照效应

三种市售医用一次性防护服的γ射线辐照后效应

高能电子束辐射交联丁腈橡胶/聚氯乙烯胶辊生胶

基于锥形束CT的直肠癌患者放疗中实际吸收剂量探讨