聚氯乙烯复合膜的制备及其紫外屏蔽性能

王冬梅; 王斌; 马祥梅; 张佳瑶; 张梦萍

doi:10.11889/j.1000-3436.2022-0136

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聚氯乙烯复合膜的制备及其紫外屏蔽性能

辐射化学 | 更新时间：2023-08-29

- 聚氯乙烯复合膜的制备及其紫外屏蔽性能
- Preparation of polyvinyl chloride composite membrane and its ultraviolet shielding properties
- 辐射研究与辐射工艺学报 2023年41卷第4期页码：40204
- 作者机构：
  
  1.安徽理工大学化工学院淮南 232001
- 作者简介：
  
  王冬梅，女，2011年11月出生，安徽理工大学在读本科生，应用化学专业
  王斌，硕士，副教授，E-mail: wb6314005@126.com
- 基金信息：
  
  大学生创新创业训练计划项目(S202210361163);安徽理工大学环境友好材料与职业健康研究院（芜湖）(ALW2020YF06)
- DOI：10.11889/j.1000-3436.2022-0136
  中图分类号：
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王冬梅, 王斌, 马祥梅, 等. 聚氯乙烯复合膜的制备及其紫外屏蔽性能[J]. 辐射研究与辐射工艺学报, 2023,41(4):040204.

WANG Dongmei, WANG Bin, MA Xiangmei, et al. Preparation of polyvinyl chloride composite membrane and its ultraviolet shielding properties[J]. Journal of Radiation Research and Radiation Processing, 2023,41(4):040204.
王冬梅, 王斌, 马祥梅, 等. 聚氯乙烯复合膜的制备及其紫外屏蔽性能[J]. 辐射研究与辐射工艺学报, 2023,41(4):040204. DOI： 10.11889/j.1000-3436.2022-0136.

WANG Dongmei, WANG Bin, MA Xiangmei, et al. Preparation of polyvinyl chloride composite membrane and its ultraviolet shielding properties[J]. Journal of Radiation Research and Radiation Processing, 2023,41(4):040204. DOI： 10.11889/j.1000-3436.2022-0136.

摘要

聚氯乙烯是广泛应用于工业、农业、家居用品等领域的通用塑料之一，具有耐磨、隔热以及成本低等诸多优点。但其在加热或紫外光（UV）辐射下容易变色、降解，限制了材料的实际应用范围。本文利用氯化铜、硫脲和聚噻吩（PTH）对纳米ZnO进行表面包裹改性，制备得到锌-铜-硫复合物，并将其分散在PVC基体中，采用流延法制得PVC复合薄膜。通过傅里叶红外光谱（FTIR）、X射线衍射（XRD）、透射电镜（TEM）和紫外分光光度计对其结构和光学性能进行了测试，探讨了纳米粒子的掺杂对PVC薄膜紫外屏蔽性能的影响。实验结果表明，功能化的ZnO纳米粒子能够明显提高PVC复合膜的紫外屏蔽能力。

Abstract

Polyvinyl chloride (PVC), which is used as one of the most widely polymer, the general purpose plastic in industry, agriculture, household items and many other fields because of abrasion resistance, thermal insulation, and low cost, etc. Nevertheless, PVC can easily change color, degrade under heating or ultraviolet (UV) light radiation because of its structural features and inherent composition, finally limited the application range of the materialist. To overcome these, the zinc- copper -sulphur composite was prepared with ZnO nanoparticle, copper chloride, thiourea and thiophene, then added to PVC solution, composite films were prepared by a casting method. Transmission electron microscopy (TEM), X-ray powder diffraction spectra (XRD), Fourier transform infrared (FTIR) and ultraviolet (UV) spectrophotometr were applied to study the structure and optical performance. The results showed that the functionalized ZnO NPs could endow the PVC composite films with excellent UV shielding capability.

关键词

聚氯乙烯紫外屏蔽纳米ZnO硫化铜聚噻吩

Keywords

Polyvinyl chlorideUltraviolet shieldingZnO nanoparticleCopper sulfidePolythiophene

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