两种共聚单体对淀粉/聚丙烯酸钠超级吸水材料耐盐性能的影响

高杨; 冯鑫鑫; 邢哲; 李林繁; 黄卫兵; 李荣; 吴国忠

doi:10.11889/j.1000-3436.2023-0018

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两种共聚单体对淀粉/聚丙烯酸钠超级吸水材料耐盐性能的影响

辐射化学 | 更新时间：2023-10-27

- 两种共聚单体对淀粉/聚丙烯酸钠超级吸水材料耐盐性能的影响
- Effect of two comonomers on salt tolerance of starch/sodium polyacrylate superabsorbent
- 辐射研究与辐射工艺学报 2023年41卷第5期页码：50204
- 作者机构：
  
  1.中国科学院上海应用物理研究所上海 201800
  2.中国科学院大学北京 100049
  3.上海长沪新材料有限公司上海 201800
  4.上海科技大学物质科学与技术学院上海 200031
- 作者简介：
  
  高杨，男，1998年2月出生，2019年于华东理工大学获学士学位，现为中国科学院上海应用物理研究所在读硕士研究生，无机化学专业
  李荣，副研究员，E-mail: lirong@sinap.ac.cn
  吴国忠，研究员，E-mail: wuguozhong@sinap.ac.cn
- 基金信息：
  
  中国科学院上海应用物理研究所重大科技项目“辐射技术在生态环境和健康领域的若干前沿应用研究”资助
- DOI：10.11889/j.1000-3436.2023-0018
  中图分类号：
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高杨, 冯鑫鑫, 邢哲, 等. 两种共聚单体对淀粉/聚丙烯酸钠超级吸水材料耐盐性能的影响[J]. 辐射研究与辐射工艺学报, 2023,41(5):050204.

GAO Yang, FENG Xinxin, XING Zhe, et al. Effect of two comonomers on salt tolerance of starch/sodium polyacrylate superabsorbent[J]. Journal of Radiation Research and Radiation Processing, 2023,41(5):050204.
高杨, 冯鑫鑫, 邢哲, 等. 两种共聚单体对淀粉/聚丙烯酸钠超级吸水材料耐盐性能的影响[J]. 辐射研究与辐射工艺学报, 2023,41(5):050204. DOI： 10.11889/j.1000-3436.2023-0018.

GAO Yang, FENG Xinxin, XING Zhe, et al. Effect of two comonomers on salt tolerance of starch/sodium polyacrylate superabsorbent[J]. Journal of Radiation Research and Radiation Processing, 2023,41(5):050204. DOI： 10.11889/j.1000-3436.2023-0018.

摘要

利用γ射线共辐照法，制备了由两种共聚单体接枝交联而成的淀粉基超级吸水材料（Super absorbent polymer，SAP）。傅里叶变换红外光谱证明了丙烯酰胺（AM）和2-丙烯酰氨基-2-甲基-1-丙烷磺酸（AMPS）分别被引入到淀粉/聚丙烯酸钠（Starch,-g-,PAA）SAP中。采用热重分析法研究了SAP的热分解行为。通过引入AM和AMPS单体，SAP的耐盐性得到显著提升，引入AMPS的SAP在生理盐水中的吸液倍率从46 g/g（未添加AMPS）提高至81 g/g（AA∶AMPS=3∶1）。

Abstract

Starch-based super absorbent polymers (SAPs) were prepared using the gamma-ray co-irradiation method, where two comonomers were grafted and cross-linked. Incorporation acrylamine (AM) and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) into the SAP was confirmed using Fourier transform infrared spectroscopy. The thermal decomposition behavior of the SAP was studied using thermogravimetric analysis. The salt tolerance was significantly improved by introducing AM and AMPS monomers into the SAP. The absorption rate of the SAP with AMPS in normal saline increased from 46 g/g (without AMPS) to 81 g/g when the ratio of AA:AMPS was 3:1.

关键词

超级吸水材料辐射接枝水溶性淀粉丙烯酸耐盐性能

Keywords

Super absorbent polymerRadiation graftingWater-soluble starchAcrylic acidSalt tolerance

references

Zhang J P, Wang A Q. Study on superabsorbent composites. Ⅸ: synthesis, characterization and swelling behaviors of polyacrylamide/clay composites based on various clays[J]. Reactive and Functional Polymers, 2007, 67(8): 737-745. DOI: 10.1016/j.reactfunctpolym. 2007.05.001http://dx.doi.org/10.1016/j.reactfunctpolym.2007.05.001.

Zheng Y A, Wang A Q. Study on superabsorbent composite. XX. Effects of cation-exchanged montmorillonite on swelling properties of superabsorbent composite containing sodium humate[J]. Polymer Composites, 2009, 30(8): 1138-1145. DOI: 10.1002/pc. 20670http://dx.doi.org/10.1002/pc.20670.

Mudiyanselage T K, Neckers D C. Highly absorbing superabsorbent polymer[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2008, 46(4): 1357-1364. DOI: 10.1002/pola.22476http://dx.doi.org/10.1002/pola.22476.

Weaver M O, Bagley E B, Fanta G F, et al. Highly absorbent starch-containing polymeric compositions: US3981100[P]. 1976-09-21.

Zhu H, Yao X. Synthesis and characterization of poly(acrylamide-co-2-acrylamido-2-methylpropane sulfonic acid)/Kaolin superabsorbent composite[J]. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 2013, 50(2): 175-184. DOI: 10.1080/10601325.2013.741891http://dx.doi.org/10.1080/10601325.2013.741891.

Chu M, Zhu S Q, Li H M, et al. Synthesis of poly(acrylic acid)/sodium humate superabsorbent composite for agricultural use[J]. Journal of Applied Polymer Science, 2006, 102(6): 5137-5143. DOI: 10.1002/app.24661http://dx.doi.org/10.1002/app.24661.

Mohana Raju K, Padmanabha Raju M. Synthesis of novel superabsorbing copolymers for agricultural and horticultural applications[J]. Polymer International, 2001, 50(8): 946-951. DOI: 10.1002/pi.721http://dx.doi.org/10.1002/pi.721.

Wang M, Xu L, Hu H, et al. Radiation synthesis of PVP/CMC hydrogels as wound dressing[J]. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 2007, 265(1): 385-389. DOI: 10.1016/j.nimb.2007.09.009http://dx.doi.org/10.1016/j.nimb.2007.09.009.

Guilherme M R, Oliveira R S, Mauricio M R, et al. Albumin release from a brain-resembling superabsorbent magnetic hydrogel based on starch[J]. Soft Matter, 2012, 8(24): 6629-6637. DOI: 10.1039/C2SM25638Jhttp://dx.doi.org/10.1039/C2SM25638J.

Ismail S A, Hegazy E S A, Shaker N O, et al. Radiation synthesis of superabsorbent hydrogels based on chitosan and acrylic acid for controlled drug release[J]. Journal of Macromolecular Science, Part A, 2009, 46(10): 967-974. DOI: 10.1080/10601320903158560http://dx.doi.org/10.1080/10601320903158560.

Kosemund K, Schlatter H, Ochsenhirt J L, et al. Safety evaluation of superabsorbent baby diapers[J]. Regulatory Toxicology and Pharmacology, 2009, 53(2): 81-89. DOI: 10.1016/j.yrtph.2008.10.005http://dx.doi.org/10.1016/j.yrtph.2008.10.005.

Adam R. Skin care of the diaper area[J]. Pediatric Dermatology, 2008, 25(4): 427-433. DOI: 10.1111/j.1525-1470.2008.00725.xhttp://dx.doi.org/10.1111/j.1525-1470.2008.00725.x.

Dutta S, Saini S S, Narang A. A comparative study of sanitary napkins and absorbent nappy pads for urine output measurement in neonates[J]. Acta Paediatrica, 2009, 98(6): 970-973. DOI: 10.1111/j.1651-2227.2009. 01277.xhttp://dx.doi.org/10.1111/j.1651-2227.2009.01277.x.

Li A, Zhang J P, Wang A Q. Preparation and slow-release property of a poly(acrylic acid)/attapulgite/sodium humate superabsorbent composite[J]. Journal of Applied Polymer Science, 2007, 103(1): 37-45. DOI: 10.1002/app.23901http://dx.doi.org/10.1002/app.23901.

司徒艳结, 卫尤明, 杨俊颖, 等. 保水剂对作物生长的不利影响及发生机制[J]. 植物营养与肥料学报, 2022, 28(7): 1318-1328. DOI: 10.11674/zwyf.2021586http://dx.doi.org/10.11674/zwyf.2021586.

SITU Yanjie, WEI Youming, YANG Junying, et al. Adverse effects of superabsorbent polymers on crop growth and the underlying mechanisms[J]. Journal of Plant Nutrition and Fertilizers, 2022, 28(7): 1318-1328. DOI: 10.11674/zwyf.2021586http://dx.doi.org/10.11674/zwyf.2021586.

Teli M D, Mallick A. Application of sorghum starch for preparing superabsorbent[J]. Journal of Polymers and the Environment, 2018, 26(4): 1581-1591. DOI: 10.1007/s10924-017-1057-7http://dx.doi.org/10.1007/s10924-017-1057-7.

Wu J H, Wei Y L, Lin J M, et al. Study on starch-graft-acrylamide/mineral powder superabsorbent composite[J]. Polymer, 2003, 44(21): 6513-6520. DOI: 10.1016/S0032-3861(03)00728-6http://dx.doi.org/10.1016/S0032-3861(03)00728-6.

Kazeminejadfard F, Hojjati M R. Preparation of superabsorbent composite based on acrylic acid-hydroxypropyl distarch phosphate and clinoptilolite for agricultural applications[J]. Journal of Applied Polymer Science, 2019, 136(16): 47365. DOI: 10.1002/app.47365http://dx.doi.org/10.1002/app.47365.

高杨, 冯鑫鑫, 李林繁, 等. 辐射法制备淀粉基超级吸水材料及其性能[J]. 辐射研究与辐射工艺学报, 2023, 41(1): 010204. DOI: 10.11889/j.1000-3436.2022-0112http://dx.doi.org/10.11889/j.1000-3436.2022-0112.

GAO Yang, FENG Xinxin, LI Linfan, et al. Preparation of a starch-based superabsorbent polymer by γ-ray irradiation and investigation of its properties[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(1): 010204. DOI: 10.11889/j.1000-3436.2022-0112http://dx.doi.org/10.11889/j.1000-3436.2022-0112.

Raafat A I, Eid M, El-Arnaouty M B. Radiation synthesis of superabsorbent CMC based hydrogels for agriculture applications[J]. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions With Materials and Atoms, 2012, 283: 71-76. DOI: 10.1016/j.nimb.2012.04.011http://dx.doi.org/10.1016/j.nimb.2012.04.011.

Ibrahim S M, El Salmawi K M, Zahran A H. Synthesis of crosslinked superabsorbent carboxymethyl cellulose/acrylamide hydrogels through electron-beam irradiation[J]. Journal of Applied Polymer Science, 2007, 104(3): 2003-2008. DOI: 10.1002/app.25916http://dx.doi.org/10.1002/app.25916.

Zhang Y N, Xu S A. Effects of amylose/amylopectin starch on starch-based superabsorbent polymers prepared by γ-radiation[J]. Starch - Stärke, 2017, 69(1/2): 1500294. DOI: 10.1002/star.201500294http://dx.doi.org/10.1002/star.201500294.

陈永利. 新疆地区盐渍土的形成机理危害性及防治措施[J]. 黑龙江科技信息, 2008(9): 21. DOI: 10.3969/j.issn.1673-1328.2008.09.022http://dx.doi.org/10.3969/j.issn.1673-1328.2008.09.022.

CHEN Yongli. Formation mechanism, harmfulness and prevention measures of saline soil in Xinjiang[J]. Scientific and Technological Innovation, 2008(9): 21. DOI: 10.3969/j.issn.1673-1328.2008.09.022http://dx.doi.org/10.3969/j.issn.1673-1328.2008.09.022.

Flory P J. Principles of polymer chemistry[M]. Ithaca: Cornell University Press, 1953.

Parvathy P C, Jyothi A N. Synthesis, characterization and swelling behaviour of superabsorbent polymers from cassava starch-graft-poly(acrylamide)[J]. Starch - Stärke, 2012, 64(3): 207-218. DOI: 10.1002/star.201100077http://dx.doi.org/10.1002/star.201100077.

Lanthong P, Nuisin R, Kiatkamjornwong S. Graft copolymerization, characterization, and degradation of cassava starch-g-acrylamide/itaconic acid superabsorbents[J]. Carbohydrate Polymers, 2006, 66(2): 229-245. DOI: 10.1016/j.carbpol.2006.03.006http://dx.doi.org/10.1016/j.carbpol.2006.03.006.

Meng Y Q, Ye L. Synthesis and swelling property of superabsorbent starch grafted with acrylic acid/2-acrylamido-2-methyl-1-propanesulfonic acid[J]. Journal of the Science of Food and Agriculture, 2017, 97(11): 3831-3840. DOI: 10.1002/jsfa.8247http://dx.doi.org/10.1002/jsfa.8247.

Xu K, Zhang W D, Yue Y M, et al. Swelling behaviors of a three-component copolymer (starch graft sodium acrylate and 2-acrylamido-2-methyl-propanosulfonic acid) synthesized by microwave polymerization[J]. Journal of Applied Polymer Science, 2005, 98(3): 1050-1054. DOI: 10.1002/app.22234http://dx.doi.org/10.1002/app.22234.

Huang Y H, Lu J, Xiao C B. Thermal and mechanical properties of cationic guar gum/poly(acrylic acid) hydrogel membranes[J]. Polymer Degradation and Stability, 2007, 92(6): 1072-1081. DOI: 10.1016/j.polymdegradstab.2007.02.011http://dx.doi.org/10.1016/j.polymdegradstab.2007.02.011.

Maurer J J, Eustace D J, Ratcliffe C T. Thermal characterization of poly(acrylic acid)[J]. Macromolecules, 1987, 20(1): 196-202. DOI: 10.1021/ma00167a035http://dx.doi.org/10.1021/ma00167a035.

Hill D J T, O'Donnell J H, Pomery P J, et al. Gamma radiolysis of poly(acrylic acid) and poly(methacrylic acid)[J]. International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry, 1992, 39(3): 237-241. DOI: 10.1016/1359-0197(92)90147-8http://dx.doi.org/10.1016/1359-0197(92)90147-8.

Luo W, Zhang W A, Chen P, et al. Synthesis and properties of starch grafted poly[acrylamide-co-(acrylic acid)]/montmorillonite nanosuperabsorbent via γ-ray irradiation technique[J]. Journal of Applied Polymer Science, 2005, 96(4): 1341-1346. DOI: 10.1002/app. 21447http://dx.doi.org/10.1002/app.21447.

Hua S B, Wang A Q. Synthesis, characterization and swelling behaviors of sodium alginate-g-poly(acrylic acid)/sodium humate superabsorbent[J]. Carbohydrate Polymers, 2009, 75(1): 79-84. DOI: 10.1016/j.carbpol. 2008.06.013http://dx.doi.org/10.1016/j.carbpol.2008.06.013.

Li T X, Kong N, Wu S S, et al. Synthesis and performance of super absorbent resin with acrylic acid-acrylamide[J]. Materials Science Forum, 2011, 687: 523-527. DOI: 10.4028/www.scientific.net/msf.687.523http://dx.doi.org/10.4028/www.scientific.net/msf.687.523.

Cipriano B H, Banik S J, Sharma R, et al. Superabsorbent hydrogels that are robust and highly stretchable[J]. Macromolecules, 2014, 47(13): 4445-4452. DOI: 10. 1021/ma500882nhttp://dx.doi.org/10.1021/ma500882n.

Awadallah-F A, Mostafa T B. Synthesis and characterization studies of γ-radiation crosslinked poly(acrylic acid/2-acrylamido-2-methyl propane sulfonic acid) hydrogels[J]. Journal of Polymer Engineering, 2014, 34(5): 459-469. DOI: 10.1515/polyeng-2013-0067http://dx.doi.org/10.1515/polyeng-2013-0067.

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