1.中国科学技术大学应用化学系 合肥 230026
2.中国科学技术大学火灾国家重点实验室 合肥 230026
贾少晋,男,1968年出生,1996年获中国科学院近代物理研究所原子核物理专业硕士学位,高分子化学与物理专业,博士研究生
张志成
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贾少晋, 张志成, 王正洲, 等. γ辐射制备阻燃HDPE/EPDM电缆材料[J]. 辐射研究与辐射工艺学报, 2002,20(1):61-66.
JIA Shaojin, ZHANG Zhicheng, WANG Zhenzhou, et al. RESEARCH ON FR-HDPE/EPDM FOR CABLE AND WIRE INSULATION BY γ RAYS[J]. Journal of Radiation Research and Radiation Processing, 2002,20(1):61-66.
以HDPE和EPDM为基体,加入低卤阻燃剂,并经γ辐照,制备了耐温125℃的阻燃电缆绝缘材料。力学及电学等测试表明,γ辐射交联可改善该材料的耐温及抗张强度等性能。用锥型量热计研究了材料交联前后的动态燃烧特性。研究发现,辐射交联可明显降低燃烧过程中热释放速率及有效燃烧热,辐射交联提高了氧指数,增加了残留成碳量,但点火时间有一定的提前。本工作将研究结果与传统的TG测定法作了比较。
By blending low —halogen flame — retarding agent with the basic resin and using γ irradiation FR — HDPE/EPDM for cable and wire insulation with 125℃ heat resistance was prepared. The mechanical and electrical measurement showed that radiation crosslinking improves some essential properties of the material, such as the heat resisteance, tensile strength ,et al,. The dynamic flammability of the material was researched by cone calorimeter,it was found that radiation crosslinking decreases both release heat rate and effective heat of combustion while burning, besides,crosslinking increases oxygen index and the residues of combustion though the time to ignition of the irradiated material is somewhat decreased. The work was compared with the tradiational method TG measurment.
锥型量热器阻燃高密度聚乙烯三元乙丙橡胶γ辐照动态燃烧特性
Cone calorimeterFlame retardantHigh—density—polyethylene(HDPE)Ethylene—propylene terpolymerγ irradiatedDynamical flame
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