THE INFLUENCE OF MOLECULAR CONFIGURATION ON DEGRADATION DEGREE IN THE RADIATION CROSSUNKING REACTION——A Review for the Applicability of Charlesby-Pinner and Chen-Liu-Tang Relationship
Sun Jiazhen. THE INFLUENCE OF MOLECULAR CONFIGURATION ON DEGRADATION DEGREE IN THE RADIATION CROSSUNKING REACTION——A Review for the Applicability of Charlesby-Pinner and Chen-Liu-Tang Relationship[J]. Journal of Radiation Research and Radiation Processing, 1983,1(1):8-16.
Sun Jiazhen. THE INFLUENCE OF MOLECULAR CONFIGURATION ON DEGRADATION DEGREE IN THE RADIATION CROSSUNKING REACTION——A Review for the Applicability of Charlesby-Pinner and Chen-Liu-Tang Relationship[J]. Journal of Radiation Research and Radiation Processing, 1983,1(1):8-16.DOI:
By comparison of the adaptability of the relationship of Charlesby-Pinner and Chen-Liu-Tang, the affection of polymer structure on its behaviour in radiation induced crosslinking was studied.,The rigid chain polymer with higher Tg (glass transition temperature) and ,σ, (hindrance factor of internal rotation) value and the polymer, containing some structure unit of radiation degradation type, obey Charlesby-Pinner relationship. The branched polymer and the flexible chain polymer with lower Tg and ,σ, value obey Chen-Liu-Tang relationship.