
1.上海市有机氟材料研究所
*.上海化学工业研究院
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汤国强, 刘钰铭. 乙烯、三氟氯乙烯与全氟丙烯辐射三元共聚合共单体全氟丙烯的影响[J]. 辐射研究与辐射工艺学报, 1983,1(1):50-56.
Tang Guoqiang, Liu Yuming. A STUDY ON RADIATION INDUCED COPOLYMERIZATION OF ETHYLENE, CHLOROTRIFLUOROETHYLENE AND HEXAFLUOROPROPENE——The effect of comonomer hexafluoropropene[J]. Journal of Radiation Research and Radiation Processing, 1983,1(1):50-56.
汤国强, 刘钰铭. 乙烯、三氟氯乙烯与全氟丙烯辐射三元共聚合共单体全氟丙烯的影响[J]. 辐射研究与辐射工艺学报, 1983,1(1):50-56. DOI:
Tang Guoqiang, Liu Yuming. A STUDY ON RADIATION INDUCED COPOLYMERIZATION OF ETHYLENE, CHLOROTRIFLUOROETHYLENE AND HEXAFLUOROPROPENE——The effect of comonomer hexafluoropropene[J]. Journal of Radiation Research and Radiation Processing, 1983,1(1):50-56. DOI:
本文主要介绍乙烯(E)、三氟氯乙烯(CTFE)与全氟丙烯(HFP)三元辐射溶液聚合时,各因素对三元共聚物的组成、熔点、熔融流动性能、物理机械性能及热老化性能的影响。其主要结果是:(1)在上述三元共聚合体系中,HFP在共聚物中含量与单体克分子比(HFP/CTFE和HFP/E)成正比关系。(2)当E/CTFE(克分子比)小于0.65,HFP/CTFE(克分子比)小于0.25时,三元共聚物的熔点大于等于235℃。(3)三元共聚物的主链上带有一定数量的-CF,3,侧基,改善了共聚物的熔融流动性能,但并不降低分子量。因而熔融指数(,M.I,.)的增加对机械性能的影响较小。其,M.I,与FC-113/共单体(重量比)(,ϕ,)、反应温度(T.℃)及HFP在共聚物中的含量(A)的关系式为:,M.I,.=10,-3.8, • ,ϕ,2.8, • T,1.78,•(41.7A),1.4,(4)三元共聚物与二元共聚物(E-CTFE)相比较,有较好的耐老化性能和相似的电性能。
This article reports the γ-ray induced copolymerization of chlorotrifluoropropene(CTFE), ethylene(E) and hexafluoropropene (HFP) in trifluorotrichloroethane (FC-113)served as solvent. It was mainly discussed how the reaction conditions affected the properties of terpolymer such as its composition, melting point, fused flowability, physicomechanical and hot-aging. The results are as follow:,1. The content of hexafluoropropene in the terpolymer increases with the mole ratios HFP/CTFE and HFP/E in the monomer feed.,2. When the value of mole ratio E/CTFE in the monomer feed is less than 0.65, and HFP/CTFE below 0.25, the melting point of the terpolymer will be≥235℃.,3. A quantity of -CF,3, pendant group connected with the backbone of the terpolymer would strengthen its fused flowability without decreasing its molecular weight. Therefore, the increase if M.I. has less influence upon its mechanical property. The relationship among the ,M.I., irradiation temperature(T), solvent feed froportion(ϕ)and hexafluoropropene content in the terpolymer(A) can be approximately shown by equation ,M.I,.=10,-3.8, • ,ϕ,2.8, • T,1.78,•(41.7A),1.4,.,4. Compared with the copolymer E-CTFE, the terpolymer possesses much better hotaging properties, but those of electricity remain unchanged.
辐射共聚合含氟三元共聚物
Radiation induced copolymerizationFluoro-containing terpolymers
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