Pan Xianming, Liu Kejian, Wu Jilan. CHARGE TRANSFER IN TBP-STILBENE TBP-TOA AND TBP-TEA MIXTURES UNDER γ-IRRADIATION[J]. Journal of Radiation Research and Radiation Processing, 1986,4(3):8-17.
Pan Xianming, Liu Kejian, Wu Jilan. CHARGE TRANSFER IN TBP-STILBENE TBP-TOA AND TBP-TEA MIXTURES UNDER γ-IRRADIATION[J]. Journal of Radiation Research and Radiation Processing, 1986,4(3):8-17.DOI:
The trans-stilbene, TOA, TEAand pyridine have been used as positive ion scavengers during γ-radiolysis of TBP. It has been found as the ionization potential of stilbene, TOA and TEA are less than that of TBP, charge transfer mechanism predominates. The experimental results were in agreement with the theoretical calculation of WAS equation. On the other hand, the ionization potential of pyridine is higher than that of TBP, energy of excitation transfer mechanism predominates.