
1.上海交通大学,上海
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王铭钧, 章士杰. 硅橡胶的辐射交联研究Ⅲ.溶胶分数与剂量的关系及乙烯基的内强化效应[J]. 辐射研究与辐射工艺学报, 1991,9(1):17-22.
Wang Mingjun, Zhang Shijie. STUDY ON THE RADIATION CROSSLINKING OF SILICONE RUBBER Ⅲ. THE RELATIONSHIP BETWEEN SOL FRACTION AND DOSE AND THE ENHANCEMENT EFFECT OF VINYL GROUP[J]. Journal of Radiation Research and Radiation Processing, 1991,9(1):17-22.
王铭钧, 章士杰. 硅橡胶的辐射交联研究Ⅲ.溶胶分数与剂量的关系及乙烯基的内强化效应[J]. 辐射研究与辐射工艺学报, 1991,9(1):17-22. DOI:
Wang Mingjun, Zhang Shijie. STUDY ON THE RADIATION CROSSLINKING OF SILICONE RUBBER Ⅲ. THE RELATIONSHIP BETWEEN SOL FRACTION AND DOSE AND THE ENHANCEMENT EFFECT OF VINYL GROUP[J]. Journal of Radiation Research and Radiation Processing, 1991,9(1):17-22. DOI:
本文合成了几种分子量相近,但乙烯基含量不同的甲基乙烯基硅橡胶。研究了辐照过程中溶胶分数与剂量之间关系。从实验上证实,在0—100kGy剂量范围内,交联度q与剂量关系为q=q,0,R,但裂解度α与剂量成,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649732&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649734&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649733&type=,关系。二甲基硅橡胶β=0.53,对各种乙烯基含量的硅橡胶β=0.44—0.54,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649735&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649737&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649736&type=,有很好线性关系。辐射交联时,从乙烯基含量与G值关系,乙烯基含量%(G值):0%(2.93),0.1%(5.14),0.20%(5.20)及0.435%(5.94),可知乙烯基的内强化效应明显。但从化学法交联效率来看,乙烯基含量%(交联效率f值):0%(0.068),0.1%(1.218),0.2%(1.983)及0.435%(3.372),可知在化学法交联过程中乙烯基内强化效应更明显。
In this present work, methyl vinyl silicone rubber (MVSR) with analogous molecular weight and various contents of vinyl group has been synthesized, and in the process of radiation crosslinking the relationship between sol fraction and dose has been studied. At 0—100 kGy dose range, it was found from experiment that the variation of degree of crosslinking (q) and degree of degradation (α) with dose may be described by the follouwing equations respectively namely q=q,0,R and ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649738&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649742&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649740&type=, β=0.53 for DMSR, and β=0.44—0.54 for MVSR with various vinyl contents.,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649743&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649745&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649756&type=, vs R,β, was provided with good linear relationship. From G-values dependence of content of vinyl group (%) (G-value): 0% (2.93), 0.1%(5.14), 0.20%(5.20) and 0.435% (5.94), inter-enhancement effect of vinyl group can be known obviously. From chemical crosslinking efficiency, content of vinyl group % (crosslinking efficiency f): 0% (0.068), 0.1% (1.218), 0.2% (1.983) and 0.435%(3.372), inter-enhancement effect is more obvious in the process of chemical crosslinking.
硅橡胶辐射交联化学交联交联的内强化效应
Silicone rubberRadiation crosslinkingChemical crosslinkingInter-enhancement effect of crosslinking
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