
1.中国科技大学,合肥
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张志成, 胡杭春, 张曼维. 丙烯酸2-乙基己酯辐射乳液聚合[J]. 辐射研究与辐射工艺学报, 1992,10(3):129-134.
Zhang Zhicheng, Hu Hangchun, Zhang Manwei. RADIATION INDUCED EMULSION POLYMERIZATION OF 2-ETHYLHEXYL ACRYLATE[J]. Journal of Radiation Research and Radiation Processing, 1992,10(3):129-134.
研究了丙烯酸2-乙基己酯辐射乳液聚合过程中反应速度与剂量率、乳化剂浓度、单体含量等因素的关系。发现反应速度与剂量率的指数依赖关系(RP∝ I,n,)随起始单体含量的增大,n值由小变大,最后趋近于1;反应速度与乳化剂浓度的0.5—0.6次方成比例。对实验结果进行了讨论,并对静态下辐射引发的乳液聚合的成核机理作了初步探讨。
The effects of radiation dose rate concentration of emulsifier and monomer content on reaction rate of radiation induced 2-ethylhexyl acrylate (EHA) emulsion polymerization have been studied. Nonionic surfactants, polyoxyethylene alkylether peregolo 0 with HLB about 15 and polyoxyethylene nonylphenolether (emulsifier OP)with HLB 15, are used as the emulsifiers in this work. It has been found that the dependence of R,p, on I (R,p,∝I,n,) is changed with the index n from 0.29 for M/W= 2/8 (monomer/water in volume) to 0.91 for 5/5, where[E] of peregolo 0 is 4%. It has also been found that R,p,∞[E],0.58, for peregolo 0 and R,p,∞[E],0.51, for emulsifier OP. In order to interpret the results sufficiently, both micellar nucleation and microdroplet nucleation have been taken into account for the emulsion polymerization of the present system irradiated without agitation, especially for the case with a higher M/W value the later may be the main nucleation process.
丙烯酸2-乙基己酯(EHA)辐射乳液聚合成核机理
2-ethylhexyl acrylate (EHA)Radiation emulsion polymerizationNucleation mechanism
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