
1.四川省原子核应用技术研究所,成都
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卓敦文, 钟光祥, 靳小燕. 蚕丝绸与N-羟甲基丙烯酰胺的γ辐照固相接枝共聚[J]. 辐射研究与辐射工艺学报, 1992,10(3):143-146.
Zhuo Dunwen, Zhong Guangxiang, Jin Xiaoyan. THE SOLID PHASE RADIATION GRAFT COPOLYMERIZATION OF N-METHYLOLACRYLAMIDE ONTO SILK FABRIC[J]. Journal of Radiation Research and Radiation Processing, 1992,10(3):143-146.
研究了N-羟甲基丙烯酰胺(NMA)在蚕丝绸上的常温γ辐照固相接枝共聚的机理和反应动力学。结果表明经50℃鼓风干燥过的蚕丝绸同NMA的固体混合物,可以发生γ辐照固相接枝。其反应由自由基型聚合和离子型聚合两部分组成。当辐照剂量率I≥2.524 kGy/h、固体混合物中NMA含量[M],<,17%、含水率[X]≤0.93%、室温时,这种固相接枝共聚的速度R,g,可以用如下方程式描述R,G,=1.373×10,-2,[M]I ,1/2,+3.209×10,-4,[M][X],-1, I。
The mechanism and kinetics of the solid phase radiation graft copolymerization of N-methylolacrylamide (NMA) onto silk fabric have been studied, The results showed that the graft copolymerization ,may, take place in the solid mixture fo silk fabric and NMA dried by air blast at 50℃. The graft copolymerization consists of two parts, i. e. radical and ionic polymerization. Under the conditions of the dose rate I≥2.524 kGy/h, NMA content [M],<,17% and moisture [X]≤0.93% in the solid mixture, and at room temperature, the rate R,g, of solid phase graft copolymerization may be described as following equation,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42650119&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42650121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42650120&type=
蚕丝绸辐照接枝N-羟甲基丙烯酰胺
Silk fabricRadiation graftN-methylolacrylamide
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