
1.福建林学院,福建南平 353001
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许洪林, 张文辉. 60Coγ辐射引发的木材自由基[J]. 辐射研究与辐射工艺学报, 1994,12(4):214-219.
Xu Honglin, Zhang Wenhui. FREE RADICALS IN WOOD INDUCED BY γ-RADIATION[J]. Journal of Radiation Research and Radiation Processing, 1994,12(4):214-219.
木材经γ辐照后,高聚物分子的共价键断裂而产生自用基。主谱g,0,=2.0193的自由基随辐射剂量D按指数率Y=1-e,αaD,规律增长,最后趋于饱和。辐射引发自由基强度与树种有关。机械自由基强度大的木屑,辐射引发自由基强度也大。
The free radicals in wood induced by γ-radiation were studied by electron spin resonance. the fine structure of the ESR signal from sawdust samples irradiated could be resolved into various radicals. These free radicals have a very long lifetime. The major spectrum for the free radicals will exponentially increased along with the radiation dose according to Y=1 - Exp(-α,a,D). The intensity of radiation radicals is dependent on tree species. The stronger the intensity of mechanic free radicals is the stronger the intensity of radiation free radicals is.
木材木屑γ辐射自由基
Wood Sawdustγ-irradiationFree radical
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