γ辐照TBP-正十二烷体系酸性长链磷酸酯的抑制

魏根栓; 吴季兰; 潘宪明

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γ辐照TBP-正十二烷体系酸性长链磷酸酯的抑制

研究论文及科研成果报告 | 更新时间：2023-04-26

- γ辐照TBP-正十二烷体系酸性长链磷酸酯的抑制
- INHIBITION OF THE FORMATION OF THE LONG CHAIN ACID PHOSPHATE IN THE γ -IRRIDIATED TBP-DODECANE SYSTEM BY ⁶⁰Co
- 辐射研究与辐射工艺学报 1986年4卷第2期页码：22-27
- 作者机构：
  
  1.北京大学
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魏根栓, 吴季兰, 潘宪明. γ辐照TBP-正十二烷体系酸性长链磷酸酯的抑制[J]. 辐射研究与辐射工艺学报, 1986,4(2):22-27.

Wei Genshuan, Wu Jilan, Pan Xianming. INHIBITION OF THE FORMATION OF THE LONG CHAIN ACID PHOSPHATE IN THE γ -IRRIDIATED TBP-DODECANE SYSTEM BY ⁶⁰Co[J]. Journal of Radiation Research and Radiation Processing, 1986,4(2):22-27.
魏根栓, 吴季兰, 潘宪明. γ辐照TBP-正十二烷体系酸性长链磷酸酯的抑制[J]. 辐射研究与辐射工艺学报, 1986,4(2):22-27. DOI：

Wei Genshuan, Wu Jilan, Pan Xianming. INHIBITION OF THE FORMATION OF THE LONG CHAIN ACID PHOSPHATE IN THE γ -IRRIDIATED TBP-DODECANE SYSTEM BY ⁶⁰Co[J]. Journal of Radiation Research and Radiation Processing, 1986,4(2):22-27. DOI：

摘要

本文通过元素分析，IR谱及MS谱等方法研究了TBP-正十二烷体系中酸性强络合辐解产物的性质和结构。用同位素示踪方法对长链酸性磷酸酯的生成机理进行了探讨并找到了能抑制长链酸性磷酸酯的有效的抑制剂。

Abstract

The nature and structure of strong complexing compounds or long chain acid phosphate formed in γ-irradiated TBP-dodecane system are studied by means of IR, MS and elements analysis. The mechanism of the formation of long chain acid phosphate and the inhibition by stilbene are investigated also. We found that stilbene is a very effective inhibitor for the radiolysis of TBP in the TBP-dodecane system.

关键词

辐解TBP正十二烷抑制剂反应芪

Keywords

RadiolysisTBPDodecaneInhibitorStilbene

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