Liu Andong. THE GAS PHASE REACTIONS OF HYDROXYL RADICALS WITH SEVERAL UNSATURATED HYDROCARBONS. [J]. Journal of Radiation Research and Radiation Processing, 1990,8(1):28-32.
Liu Andong. THE GAS PHASE REACTIONS OF HYDROXYL RADICALS WITH SEVERAL UNSATURATED HYDROCARBONS. [J]. Journal of Radiation Research and Radiation Processing, 1990,8(1):28-32.DOI:
本文简要介绍了利用脉冲辐解技术研究OH自由基与不饱和碳氢化合物气相反应的基本原理。报道了在101325 Pa
300-1200 K温度范围内OH自由基与乙炔、乙烯、丙烯、1-丁烯,氯乙烯、丙二烯及1
3-丁二烯气相反应速度常数随温度的变化,并对这些反应的机理作了简单讨论。
Abstract
The principal of using pulse radiolysis technique to study the gas phase reactions of OH radicals with unsaturated hydrocarbons is described brifly in this paper. The temperature dependence of the rate constants of OH radicals with acetylene
ethylene
vinylchloride
propylene
1-butene
allene and 1
3-butadiene is reported. Short discussion was given to the reaction mechanism.