Radiolysis mechanisms of N,N,N’,N’-tetrabutyl-3-oxa-pentanediamide

ZHANG Xiaolan; BAO Borong; YE Guoan; ZHANG Xianye

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Radiolysis mechanisms of N,N,N’,N’-tetrabutyl-3-oxa-pentanediamide

更新时间：2023-03-30

- Radiolysis mechanisms of N,N,N’,N’-tetrabutyl-3-oxa-pentanediamide
- Journal of Radiation Research and Radiation Processing Vol. 23, Issue 5, Pages: 292-295(2005)
- 作者机构：
  
  1.中国科学院上海应用物理研究所　上海　201800
  2.上海大学环境与化学工程学院　上海　200072
  3.上海大学理学院　上海　200444
  4.中国原子能科学研究院放射化学研究所　北京　102413
- 作者简介：
- 基金信息：
- DOI：
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ZHANG Xiaolan, BAO Borong, YE Guoan, et al. Radiolysis mechanisms of N,N,N’,N’-tetrabutyl-3-oxa-pentanediamide. [J]. Journal of Radiation Research and Radiation Processing 23(5):292-295(2005)
DOI：

ZHANG Xiaolan, BAO Borong, YE Guoan, et al. Radiolysis mechanisms of N,N,N’,N’-tetrabutyl-3-oxa-pentanediamide. [J]. Journal of Radiation Research and Radiation Processing 23(5):292-295(2005) DOI：

摘要

计算了N,N,N’,N’-四丁基-3-氧-戊二酰胺（N,N,N’,N’-tetrabutyl-3-oxa-pentanediamide, TBOPDA）中各个原子的电荷分布，根据电荷分布情况讨论了TBOPDA中有关化学键的相对稳定性和可能断裂几率，认为TBOPDA中化学键的辐照稳定程度为C-O

Abstract

The partial electron of atoms in N,N,N',N'-tetrabutyl-3-oxa-pentanediamide (TBOPDA) was calculated with MM+ codes. The stability and cleavability of different single-bonds were discussed, with the radiation stability being C-O < C-< C-N < C-C. The calculation results were confirmed experimentally by G values of radiolysis products of TBOPDA samples, which were measured by solid phase micro-extraction and gas chromatography.

关键词

辐照效应NNN’N’-四丁基-3-氧-戊二酰胺电荷分布产额

Keywords

RadiationNNN’N’-tertbutyl-3-oxa-entanediamidePartial electron of atomG value

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