A STUDY ON THE RATE CONSTANT OF EXCITED ENERGY TRANSFER FROM CYCLOHEXANE EXCITED STATE TO TRIOCTYL PHOSPHINE OXIDE

QU Bo; WU Jilan; WANG Wenqing

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A STUDY ON THE RATE CONSTANT OF EXCITED ENERGY TRANSFER FROM CYCLOHEXANE EXCITED STATE TO TRIOCTYL PHOSPHINE OXIDE

更新时间：2023-04-07

- A STUDY ON THE RATE CONSTANT OF EXCITED ENERGY TRANSFER FROM CYCLOHEXANE EXCITED STATE TO TRIOCTYL PHOSPHINE OXIDE
- Journal of Radiation Research and Radiation Processing Vol. 19, Issue 1, Pages: 32-35(2001)
- 作者机构：
  
  1.北京大学技术物理系　北京　100871
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QU Bo, WU Jilan, WANG Wenqing. A STUDY ON THE RATE CONSTANT OF EXCITED ENERGY TRANSFER FROM CYCLOHEXANE EXCITED STATE TO TRIOCTYL PHOSPHINE OXIDE. [J]. Journal of Radiation Research and Radiation Processing 19(1):32-35(2001)
DOI：

QU Bo, WU Jilan, WANG Wenqing. A STUDY ON THE RATE CONSTANT OF EXCITED ENERGY TRANSFER FROM CYCLOHEXANE EXCITED STATE TO TRIOCTYL PHOSPHINE OXIDE. [J]. Journal of Radiation Research and Radiation Processing 19(1):32-35(2001) DOI：

摘要

用终产物分析的方法研究了环己烷（CH）—三辛基氧化膦（TOPO）体系在γ辐解过程中环己烷激发态能量传递的速率常数。结果表明，此过程中激发能传递的速率常数为1.9×10,10, L•mol•s,-1,，略高于一般的扩散控制过程。

Abstract

The rate constant of excited energy transfer in the ,γ, radiolysis of CH—TOPO system was studied by final product analysis. The results showed that the rate constant for the system was 1.9×10,10, L•mol•s,-1, which was a little larger than that of an ordinary diffusion—controlled process.

关键词

环己烷三辛基氧化膦γ辐解能量传递扩散控制超常速率

Keywords

Cyclohexane (CH)Trioctyl phosphine oxide (TOPO)γ radiolysisEnergy transferDiffusion—controlledAbnormal rate constant

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Department of Applied of Chemistry and Molecular Enging, Peking University

Minfu Science and Technology Development Co. Ltd, Postdoctor Working Station in High Technology Area of Jinjiang

Department of physics Technical Peking University.

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