THE INFLUENCE OF MOLECULAR CONFIGURATION ON DEGRADATION DEGREE IN THE RADIATION CROSSUNKING REACTION——A Review for the Applicability of Charlesby-Pinner and Chen-Liu-Tang Relationship

Sun Jiazhen

您当前的位置：

首页 >

文章列表页 >

THE INFLUENCE OF MOLECULAR CONFIGURATION ON DEGRADATION DEGREE IN THE RADIATION CROSSUNKING REACTION——A Review for the Applicability of Charlesby-Pinner and Chen-Liu-Tang Relationship

更新时间：2023-04-18

- THE INFLUENCE OF MOLECULAR CONFIGURATION ON DEGRADATION DEGREE IN THE RADIATION CROSSUNKING REACTION——A Review for the Applicability of Charlesby-Pinner and Chen-Liu-Tang Relationship
- Journal of Radiation Research and Radiation Processing Vol. 1, Issue 1, Pages: 8-16(1983)
- 作者机构：
  
  1.中国科学院长春应用化学研究所
- 作者简介：
- 基金信息：
- DOI：
  CLC：
扫描看全文
Sun Jiazhen. THE INFLUENCE OF MOLECULAR CONFIGURATION ON DEGRADATION DEGREE IN THE RADIATION CROSSUNKING REACTION——A Review for the Applicability of Charlesby-Pinner and Chen-Liu-Tang Relationship. [J]. Journal of Radiation Research and Radiation Processing 1(1):8-16(1983)
DOI：

Sun Jiazhen. THE INFLUENCE OF MOLECULAR CONFIGURATION ON DEGRADATION DEGREE IN THE RADIATION CROSSUNKING REACTION——A Review for the Applicability of Charlesby-Pinner and Chen-Liu-Tang Relationship. [J]. Journal of Radiation Research and Radiation Processing 1(1):8-16(1983) DOI：

摘要

比较Charlesby-Pinner及陈欣方-刘克静-唐敖庆（简称陈-刘-唐）关系式在高分子辐射交联反应中的适用情况，研究了高分子链结构对辐射交联反应的影响。具有较高的Tg(玻璃化转变温度）及,σ,（内旋转位阻因子）值的刚性链高分子和结构单元中含有辐射裂解型单体的高分子，符合Charlesby-Pinner关系式。支化高分子和具有较低的Tg及,σ,值的柔性链高分子符合陈-刘-唐关系式。

Abstract

By comparison of the adaptability of the relationship of Charlesby-Pinner and Chen-Liu-Tang, the affection of polymer structure on its behaviour in radiation induced crosslinking was studied.,The rigid chain polymer with higher Tg (glass transition temperature) and ,σ, (hindrance factor of internal rotation) value and the polymer, containing some structure unit of radiation degradation type, obey Charlesby-Pinner relationship. The branched polymer and the flexible chain polymer with lower Tg and ,σ, value obey Chen-Liu-Tang relationship.

关键词

Charlesby-Pinner关系式陈-刘-唐关系式刚性链高分子柔性链高分子支化高分子辐射交联高分子结构玻璃化转变温度内旋转位阻因子

Keywords

Charlesby-Pinner relationshipChen-Liu-Tang relationshipRigid chain polymerFlexible chain polymerBranched polymerRadiation induced crosslinkingPolymer structureGlass transition temperatureHindrance factor of internal rotation

references

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

A RESEARCH OF RADIATION EFFECTS ON PVF₂ /PEA BLEND SYSTEM

THE EFFECT OF FLEXIBILITY OF FLUOROPOLYMERS ON THEIR RADIATION CROSSLINKING BEHAVIOR

THE STRUCTURE EFFECTS ON THE FRACTURE DENSITY IN RADIATION INDUCED CROSSLINKING OF POLYMERS The relationship between sol fraction and radiation dose

Related Author

No data

Related Institution

Chaungchn Institute of Applied Chemistry, Acodemia Sinica

⁰