RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE- Ⅰ, NUCLEATION MODEL

Zhang Wanxi; Sun Jiazhen

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RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE- Ⅰ, NUCLEATION MODEL

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- RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE- Ⅰ, NUCLEATION MODEL
- Journal of Radiation Research and Radiation Processing Vol. 3, Issue 2, Pages: 1-5(1985)
- 作者机构：
  
  1.中国科学院长春应用化学研究所
- 作者简介：
- 基金信息：
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Zhang Wanxi, Sun Jiazhen. RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE- Ⅰ, NUCLEATION MODEL. [J]. Journal of Radiation Research and Radiation Processing 3(2):1-5(1985)
DOI：

Zhang Wanxi, Sun Jiazhen. RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE- Ⅰ, NUCLEATION MODEL. [J]. Journal of Radiation Research and Radiation Processing 3(2):1-5(1985) DOI：

摘要

本文通过测定聚合反应初期的胶乳粒子直径分布，在临界胶束浓度以上的聚合反应速率与乳化剂浓度的关系以及聚合物胶乳的分子量分布，研究了苯乙烯辐射乳液聚合的成核方式。从实验上证实了其成核方式是既有水相成核又有胶束成核。

Abstract

The nucleation model for radiation-induced emulsion polymerization of styrene has been studied by measurement of diameter distribution of latex particles during primary stage of polymerization reaction and by the relationship between polymerization rate and emulsifier concentration, and the molecular weight distribution below the critical micelle concentration.,It is shown that the nucleation model is both aqueous nucleation and micellar nucleation from the experiment.

关键词

辐射乳液聚合苯乙烯胶束成核水相成核

Keywords

Radiation-induced emulsion polymerizationStyreneMicellar nucleationAqueous nucleation

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