RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE-Ⅱ. KINETICS OF POLYMERIZATION REACTION

Zhang Wanxi; Sun Jiazhen

您当前的位置：

首页 >

文章列表页 >

RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE-Ⅱ. KINETICS OF POLYMERIZATION REACTION

更新时间：2023-04-23

- RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE-Ⅱ. KINETICS OF POLYMERIZATION REACTION
- Journal of Radiation Research and Radiation Processing Vol. 3, Issue 4, Pages: 1-10(1985)
- 作者机构：
  
  1.中国科学院长春应用化学研究所
- 作者简介：
- 基金信息：
- DOI：
  CLC：
扫描看全文
Zhang Wanxi, Sun Jiazhen. RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE-Ⅱ. KINETICS OF POLYMERIZATION REACTION. [J]. Journal of Radiation Research and Radiation Processing 3(4):1-10(1985)
DOI：

Zhang Wanxi, Sun Jiazhen. RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE-Ⅱ. KINETICS OF POLYMERIZATION REACTION. [J]. Journal of Radiation Research and Radiation Processing 3(4):1-10(1985) DOI：

摘要

本文在前文所设想的成核模型基础上，建立了聚合反应动力学模型公式，其聚合反应第Ⅱ阶段总转化率表达式如下：,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648353&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648355&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648354&type=,A和B分别为胶束成核和水相成核分数。,用本文的动力学模型公式计算出的转化率～时间曲线，粒子数，聚合度与实验结果相符。

Abstract

The kinetic model equations of radiation-induced emulsion polymerization of styrene have been established, according to the nucleation model suggested in above paper. The monomer conversion in stage of region Ⅱ for the polymerization reaction is given as follows:,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648356&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648373&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42648357&type=,Where A——fraction of micellar nucleation;,B——fraction of aqueous nucleation.,The curve of monomer conversion against polymerrization time, number of polymer particles and degree of polymerization calculated by these model equations are in agreement with the experimental results.

关键词

苯乙烯辐射乳液聚合聚合反应动力学

Keywords

StyreneRadiation-induced emulsion polymerizationKinetics of polymerization reaction

references

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

THE PREPARATION OF MONODISPERSE POLYSTYRENE LATICES

RADIATION INDUCED EMULSION POLYMERIZATION OF STYRENE IN SOAP-FREE SYSTEM

RADIATION-INDUCED EMULSION POLYMERIZATION OF STYRENE- Ⅰ, NUCLEATION MODEL

Radiation grafting of styrene into PVDF powder

Study of maleic anhydride and styrene grafted onto polypropylene induced by UV irradiation

Related Author

No data

Related Institution

Chagchun Institute of Applied Chemistry, Academia Sinica

Shanghai Institute of Applied Physics, Chinese Academy of Sciences

Graduate School of Chinese Academy of Sciences

College of Materials Science and Engineering, Beijing University of Technology

Institute of Polymeric Material, North University of China, Ying Xin Branch

⁰