CHARGE TRANSFER IN TBP-STILBENE TBP-TOA AND TBP-TEA MIXTURES UNDER γ-IRRADIATION

Pan Xianming; Liu Kejian; Wu Jilan

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CHARGE TRANSFER IN TBP-STILBENE TBP-TOA AND TBP-TEA MIXTURES UNDER γ-IRRADIATION

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- CHARGE TRANSFER IN TBP-STILBENE TBP-TOA AND TBP-TEA MIXTURES UNDER γ-IRRADIATION
- Journal of Radiation Research and Radiation Processing Vol. 4, Issue 3, Pages: 8-17(1986)
- 作者机构：
  
  1.北京大学
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Pan Xianming, Liu Kejian, Wu Jilan. CHARGE TRANSFER IN TBP-STILBENE TBP-TOA AND TBP-TEA MIXTURES UNDER γ-IRRADIATION. [J]. Journal of Radiation Research and Radiation Processing 4(3):8-17(1986)
DOI：

Pan Xianming, Liu Kejian, Wu Jilan. CHARGE TRANSFER IN TBP-STILBENE TBP-TOA AND TBP-TEA MIXTURES UNDER γ-IRRADIATION. [J]. Journal of Radiation Research and Radiation Processing 4(3):8-17(1986) DOI：

摘要

用,60,Co γ源辐照TBP体系，研究了TBP与溶质分子反式二苯乙烯、TOA、TEA、吡啶的能量转移机理。实验发现，在能量接受体（反式二苯乙烯，三烷基胺）的电离电位低于TBP的电离电位时，电荷转移反应是能量传递的主要形式。

Abstract

The trans-stilbene, TOA, TEAand pyridine have been used as positive ion scavengers during γ-radiolysis of TBP. It has been found as the ionization potential of stilbene, TOA and TEA are less than that of TBP, charge transfer mechanism predominates. The experimental results were in agreement with the theoretical calculation of WAS equation. On the other hand, the ionization potential of pyridine is higher than that of TBP, energy of excitation transfer mechanism predominates.

关键词

γ辐照TBP电荷转移

Keywords

γ-irradiationTBPCharge transfer

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