STUDY ON THE RADIATION CROSSLINKING OF SILICONE RUBBER Ⅲ. THE RELATIONSHIP BETWEEN SOL FRACTION AND DOSE AND THE ENHANCEMENT EFFECT OF VINYL GROUP
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STUDY ON THE RADIATION CROSSLINKING OF SILICONE RUBBER Ⅲ. THE RELATIONSHIP BETWEEN SOL FRACTION AND DOSE AND THE ENHANCEMENT EFFECT OF VINYL GROUP
Journal of Radiation Research and Radiation ProcessingVol. 9, Issue 1, Pages: 17-22(1991)
作者机构:
1.上海交通大学,上海
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Wang Mingjun, Zhang Shijie. STUDY ON THE RADIATION CROSSLINKING OF SILICONE RUBBER Ⅲ. THE RELATIONSHIP BETWEEN SOL FRACTION AND DOSE AND THE ENHANCEMENT EFFECT OF VINYL GROUP. [J]. Journal of Radiation Research and Radiation Processing 9(1):17-22(1991)
DOI:
Wang Mingjun, Zhang Shijie. STUDY ON THE RADIATION CROSSLINKING OF SILICONE RUBBER Ⅲ. THE RELATIONSHIP BETWEEN SOL FRACTION AND DOSE AND THE ENHANCEMENT EFFECT OF VINYL GROUP. [J]. Journal of Radiation Research and Radiation Processing 9(1):17-22(1991)DOI:
STUDY ON THE RADIATION CROSSLINKING OF SILICONE RUBBER Ⅲ. THE RELATIONSHIP BETWEEN SOL FRACTION AND DOSE AND THE ENHANCEMENT EFFECT OF VINYL GROUP
In this present work, methyl vinyl silicone rubber (MVSR) with analogous molecular weight and various contents of vinyl group has been synthesized, and in the process of radiation crosslinking the relationship between sol fraction and dose has been studied. At 0—100 kGy dose range, it was found from experiment that the variation of degree of crosslinking (q) and degree of degradation (α) with dose may be described by the follouwing equations respectively namely q=q,0,R and ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649738&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649742&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649740&type=, β=0.53 for DMSR, and β=0.44—0.54 for MVSR with various vinyl contents.,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649743&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649745&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=42649756&type=, vs R,β, was provided with good linear relationship. From G-values dependence of content of vinyl group (%) (G-value): 0% (2.93), 0.1%(5.14), 0.20%(5.20) and 0.435% (5.94), inter-enhancement effect of vinyl group can be known obviously. From chemical crosslinking efficiency, content of vinyl group % (crosslinking efficiency f): 0% (0.068), 0.1% (1.218), 0.2% (1.983) and 0.435%(3.372), inter-enhancement effect is more obvious in the process of chemical crosslinking.
关键词
硅橡胶辐射交联化学交联交联的内强化效应
Keywords
Silicone rubberRadiation crosslinkingChemical crosslinkingInter-enhancement effect of crosslinking