THE STRUCTURE CHARACTER OF THE PLASMA COPOLYMERS OF VINYLTRIMETHYLSILANE WITH BENZEME, STYRENE AND HEXAFLUOROPROPYLENE

Yan Wenge; Chen Jie

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THE STRUCTURE CHARACTER OF THE PLASMA COPOLYMERS OF VINYLTRIMETHYLSILANE WITH BENZEME, STYRENE AND HEXAFLUOROPROPYLENE

更新时间：2023-04-23

- THE STRUCTURE CHARACTER OF THE PLASMA COPOLYMERS OF VINYLTRIMETHYLSILANE WITH BENZEME, STYRENE AND HEXAFLUOROPROPYLENE
- Journal of Radiation Research and Radiation Processing Vol. 10, Issue 1, Pages: 30-35(1992)
- 作者机构：
  
  1.沈阳药学院，沈阳
  2.中国科学院长春应用化学研究所，长春
- 作者简介：
- 基金信息：
  
  National Nature Science Foundation of China
- DOI：
  CLC：
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Yan Wenge, Chen Jie. THE STRUCTURE CHARACTER OF THE PLASMA COPOLYMERS OF VINYLTRIMETHYLSILANE WITH BENZEME, STYRENE AND HEXAFLUOROPROPYLENE. [J]. Journal of Radiation Research and Radiation Processing 10(1):30-35(1992)
DOI：

Yan Wenge, Chen Jie. THE STRUCTURE CHARACTER OF THE PLASMA COPOLYMERS OF VINYLTRIMETHYLSILANE WITH BENZEME, STYRENE AND HEXAFLUOROPROPYLENE. [J]. Journal of Radiation Research and Radiation Processing 10(1):30-35(1992) DOI：

摘要

采用外部电极电容耦合的RF辉光放电装置研究了乙烯基三甲基硅烷（VTMS）与苯（Bz）、苯乙烯（St）以及六氟丙烯（HFP）的等离子体共聚合。用IR、ESCA、PGC/MS和X射线对聚合物结构进行表征，证明乙烯基三甲基硅烷与苯、苯乙烯以及六氟丙烯可进行共聚合。C/Si比的增加表明苯、苯乙烯和六氟丙烯的嵌入导致聚合物组成的变化，Si含量相对较低。共聚物中无Si-H键的形成。

Abstract

In a capacitively coupled RF glow discharge with external electrodes plasma copolymerizations of vinyltrimethylsilane (VTMS) with benzene(Bz), styrene(St) and hexafluoropropylene(HFP) were carried out.The structures of the copolymers were characterized with IR, ESCA, PGC/MS, and X-ray. It was found that the copolymerizations of VTMS with Bz, St and HFP have occurred. The increase of C/Si ratios of the copolymer indicates that the incorporation of Bz, St and HFP caused the change of the copolymer composition, and as a result, the Si content of the copolymer is relatively low. Si-H absorption peak does'nt appear in IR spectra.

关键词

等离子体共聚合乙烯基三甲基硅烷红外光谱电子能谱裂解色谱-质谱表征

Keywords

PlasmaCopolymerizationVinyltrimethylsilaneIRESCAPGC/MSCharacter

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