SPECTRAL STUDIES OF DERIVATIVE OF TRICYCLIC MODIFIED NUCLEOSIDE IN AQUEOUS SOLUTIONS

ZHAO Hongwei; DOU Daying; MIAO Jinling; YAO Side; JIANG Zhiqin; ZHAO Chunlei

您当前的位置：

首页 >

文章列表页 >

SPECTRAL STUDIES OF DERIVATIVE OF TRICYCLIC MODIFIED NUCLEOSIDE IN AQUEOUS SOLUTIONS

更新时间：2023-05-04

- SPECTRAL STUDIES OF DERIVATIVE OF TRICYCLIC MODIFIED NUCLEOSIDE IN AQUEOUS SOLUTIONS
- Journal of Radiation Research and Radiation Processing Vol. 20, Issue 4, Pages: 241-245(2002)
- 作者机构：
  
  1.中国科学院上海原子核研究所辐射化学开放实验室　上海　201800
  2.同济大学化学系　上海　200092
- 作者简介：
- 基金信息：
- DOI：
  CLC：
扫描看全文
ZHAO Hongwei, DOU Daying, MIAO Jinling, et al. SPECTRAL STUDIES OF DERIVATIVE OF TRICYCLIC MODIFIED NUCLEOSIDE IN AQUEOUS SOLUTIONS. [J]. Journal of Radiation Research and Radiation Processing 20(4):241-245(2002)
DOI：

ZHAO Hongwei, DOU Daying, MIAO Jinling, et al. SPECTRAL STUDIES OF DERIVATIVE OF TRICYCLIC MODIFIED NUCLEOSIDE IN AQUEOUS SOLUTIONS. [J]. Journal of Radiation Research and Radiation Processing 20(4):241-245(2002) DOI：

摘要

利用时间分辨激光光解技术对稀有三环核苷的前体化合物N-4-desmethylwyosine(dYt)研究发现 ,该化合物能被248nm激光单光子电离 ,但未观察到明显的激发三线态。用氧化性自由基SO,4,·-,引发其阳离子自由基 ,揭示了其光电离机理。以KI溶液为参照,测得该化合物中性条件下的光电离量子产额 (Φ,e,-, )为 0.04。

Abstract

The absorption spectra of N-4-desmethylwyosine (dYt), a derivative of the tricyclic modified nucleoside wyosine, in aqueous solutions were studied by time-resolved laser photolysis. The oxidizing radical SO,4,·-, was used to produce dYt radical cation. The mechanism of dYt monophotonic ionization was suggested. Distinct triplet was not observed in this work. The quantum yield of formation of hydrated electrons (Φ,e,-,) was determined to be 0.04 at room temperature in neutral aqueous solution by using KI solution as a reference.

关键词

稀有三环核苷衍生物单光子电离自由基激光光解瞬态吸收光谱

Keywords

Derivative of tricyclic modified nucleosideMonophotonic ionizationRadicalLaser photolysisTransient absorption spectrum

references

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

A STUDY ON THE LASER FLASH PHOTOLYSIS OF FULLEROL OF C₇₀ IN AQUEOUS SOLUTION

Pulse radiolysis of aqueous N, N-Dimethylhydroxylamine solutions

Photo-induced electron transfer from triplet TMB to electron poor olefins

Fast reaction kinetics of ^•OH with the derivative of rare tricyclic nucleoside and theoretical calculation

STUDY OF LASER PHOTOLYSIS OF P-TERT-OXOCALIX[4] ARENE

Related Author

No data

Related Institution

Laboratory of Radiation Chemistry, Shanghai Institute of Nuclear Research,The Chinese Academy of Sciences

Nuclear Analysis Center, Shanghai Institute of Nuclear Research, The Chinese Academy of Sciences

Institute of Radiochemistry, China Institute of Atomic Energy

Shanghai Institute of Applied Physics, Chinese Academy of Sciences

Laboratory of Bond-selective Chemistry, Department of Chemical Physics, University of Science and Technology of China

⁰