
1.上海科学技术大学
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刘钰铭. 研究辐射聚合动力学的几种膨胀计[J]. 辐射研究与辐射工艺学报, 1986,4(3):58-62.
Liu Yuming. SOME DILATOMETER ON KINETIC STUDY OF RADIATION-INDUCED POLYMERIZATION[J]. Journal of Radiation Research and Radiation Processing, 1986,4(3):58-62.
本文介绍了研究辐射聚合动力学的三种膨胀计系统。(1)常压膨胀计,它适用于常压下的均聚合及共聚合反应;(2)压力下本体聚合膨胀计,它适用于10 kg/cm,2,压力以下进行的本体均聚合及共聚合;(3)压力下溶液聚合膨胀计,它适用于10 kg/cm,2,压力以下进行的溶液聚合及共聚合。这三种膨胀计皆用硬质玻璃制成,制造简易,使用方便,可以远距离测量和自动记录。这些膨胀计不但能描绘聚合的初期过程,而且能准确地测定自动加速以后的聚合过程。
The three systems of dilatometer on kinetic study of radiation induced polymerization are presented.,(1) The atmospheric dilatometer. It is suited to determine the homogeneous polymerization and copolymerization process under atmospheric polymerization.,(2) The pressure dilatometer of bulk polymerization. It is suited to determine the bulk homogeneous polymerization and copolymerization process under 10 kg/cm,2, such as radiation induced bulk polymerization of some fluoro-alkene monomers.,(3) The pressure dilatometer of solvent polymerization.,It is suited to determine the solvent polymerization and copolymerization process under 10 Kg/cm,2, such as radiationinduced copolymerization of Chlorotrifluoroethylene(CTFE) and ethylene(E) in trifluorotrichloroethane (FC-113) .,All of the above-mentioned delatometers are made of hard glass, and they are simple in construction, easy to handle, measuring at long-distance and recording by automatic recorder. In addition, the abovementioned dilatometers not can only measure the initial polymerization process, but can also measure the autocatalytis reaction after gel effect.
常压膨胀计压力膨胀计膨胀泡预辐照聚合聚合动力学
Atmospheric dilatometerPressure dilatometerDilatometer bulbPreirradiation polymerizationPolymerization kinetic
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