SOLVENT EFFECT ON GRAFT POLYMERIZATION OF NIPAAm ONTO COTTOM CELLULOSE VIA γ PREIRRADIATION METHOD
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SOLVENT EFFECT ON GRAFT POLYMERIZATION OF NIPAAm ONTO COTTOM CELLULOSE VIA γ PREIRRADIATION METHOD
Journal of Radiation Research and Radiation ProcessingVol. 18, Issue 2, Pages: 124-128(2000)
作者机构:
1.北京大学技术物理系 北京 100871
作者简介:
基金信息:
Foundation of Nuclear Science(Y7197FY006)
DOI:
CLC:
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LU Jun, ZHAI Maolin, YI Min, et al. SOLVENT EFFECT ON GRAFT POLYMERIZATION OF NIPAAm ONTO COTTOM CELLULOSE VIA γ PREIRRADIATION METHOD. [J]. Journal of Radiation Research and Radiation Processing 18(2):124-128(2000)
DOI:
LU Jun, ZHAI Maolin, YI Min, et al. SOLVENT EFFECT ON GRAFT POLYMERIZATION OF NIPAAm ONTO COTTOM CELLULOSE VIA γ PREIRRADIATION METHOD. [J]. Journal of Radiation Research and Radiation Processing 18(2):124-128(2000)DOI:
SOLVENT EFFECT ON GRAFT POLYMERIZATION OF NIPAAm ONTO COTTOM CELLULOSE VIA γ PREIRRADIATION METHOD
Graft polymerization of N-isopropylacrylamide (NIPAAm) onto cotton cellulose preirradiated in air by ,60,Co γ rays was accomplished in mixed solvents of water and alcohols or acetone. The graft yields changed with different ratios of water and organic solvents. In the system of solvents comprised of water and methanol, the Trommsdorff effect appeared in the curve of the graft yields vice verse the concentrations of the monomer. In the same system, the dependence of the graft yield of NIPAAm on the graft temperature was different from that of Acrylamide (AAm). The relation between the graft yields of the grafted products and their crystallinities measured by X Ray Diffraction could be regarded as a proof of the 'third phase' conception.