RADIATION POLYMERIZATION OF TRIBUTYL TIN METHACRYLATE

Zao Benxi; Murat; Zun Sionbu; Han Zhewen

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RADIATION POLYMERIZATION OF TRIBUTYL TIN METHACRYLATE

更新时间：2023-04-23

- RADIATION POLYMERIZATION OF TRIBUTYL TIN METHACRYLATE
- Journal of Radiation Research and Radiation Processing Vol. 4, Issue 4, Pages: 23-28(1986)
- 作者机构：
  
  1.中国科学技术大学
- 作者简介：
- 基金信息：
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Zao Benxi, Murat, Zun Sionbu, et al. RADIATION POLYMERIZATION OF TRIBUTYL TIN METHACRYLATE. [J]. Journal of Radiation Research and Radiation Processing 4(4):23-28(1986)
DOI：

Zao Benxi, Murat, Zun Sionbu, et al. RADIATION POLYMERIZATION OF TRIBUTYL TIN METHACRYLATE. [J]. Journal of Radiation Research and Radiation Processing 4(4):23-28(1986) DOI：

摘要

本文介绍了用,60,Co γ辐射引发聚合合成纯度较高的聚甲基丙烯酸三丁基锡酯（PTBTM），并对它的辐射聚合反应动力学进行了研究。结果表明TBTM浓度与聚合反应速率R,p,之间的关系为R,p, =K,p,[TBTM],2,；辐射剂量率Ⅰ与反应速率之间的关系为R,p,=K',p,I,0.66,；辐射聚合反应的表观活化能E,a,为3.12 J/mol。本文还对聚合反应的机制进行了探讨。

Abstract

This paper introduced the Radiation Polymerization of Polytributyltin Methacrylate (PTBTM) and its kinetics. The results are shown Fig1~6. The relationship between rate R,p, and Concentration of TBTM are shown R,p,=K,p,[TBTM],2, The relation dose rate I and rate R,p, are shown R,p,=K',p,I,0.66,. The overall activation energy of polymerization E,a, is 1.32 J/mol. This paper also investigates the machine of polymerization for TBTM.

关键词

辐射聚合聚合速率转化率自由基甲基丙烯酸三丁基锡酯聚合反应活化能

Keywords

Radiation PolymerizationPolymerization rateConversion rateRadical Tributyl Tin MethacrylateActivation energy of polymerization

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