THE RADIATION CROSSLINKING OF ETHYLENE-PROPYLENE COPOLYMER
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THE RADIATION CROSSLINKING OF ETHYLENE-PROPYLENE COPOLYMER
Journal of Radiation Research and Radiation ProcessingVol. 5, Issue 1, Pages: 21-26(1987)
作者机构:
1.中国科学院长春应用化学研究所
2.吉林大学
作者简介:
基金信息:
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Li Shuzhong, He Zhongda, Zhang Zicheng, et al. THE RADIATION CROSSLINKING OF ETHYLENE-PROPYLENE COPOLYMER. [J]. Journal of Radiation Research and Radiation Processing 5(1):21-26(1987)
DOI:
Li Shuzhong, He Zhongda, Zhang Zicheng, et al. THE RADIATION CROSSLINKING OF ETHYLENE-PROPYLENE COPOLYMER. [J]. Journal of Radiation Research and Radiation Processing 5(1):21-26(1987)DOI:
THE RADIATION CROSSLINKING OF ETHYLENE-PROPYLENE COPOLYMER
This paper reports the radiation crosslinking reaction of three-component ethylene-propylene copolymer (EPDM). The reaction taking place in random at high dose range obeyes Charlesby-Pinner equation and Chen-Liu-Tang equation. At low dose range radiation crosslinking of EPDM is enhanced due to the presence of third monomer (bis-(cyclopentadiene)) which accelerates the reaction with its double bond. The radiation crosslirking reaction is also accelerated by the addition of MI. The radiation crosslinked EPDM containing 50-70% gel was obtained with the addition of 1% MI in 2-4 Mrad dose range.,The structures and properties of the radiation crosslinked EPDM were measured. The mechanical property and thermal property had been improved. The tg δ maintains in the order of 10,-3,.,It is expected that the radiation crosslinked EPDM may be a promising material for making insulated wire, cable and heat shrinkable tubing.
关键词
乙丙共聚物(EPDM)辐射交联Charlesby-Pinner关系式
Keywords
Copolymer of ethylene-propylene (EPDM)Radiation crosslinkingCharlesby-Pinner equation