RADIATION POLYMERIZATION OF ACRYLAMIDE IN SOLID STATE

Xu Hansheng; Zhang Zhicheng; Jin Yunzheng

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RADIATION POLYMERIZATION OF ACRYLAMIDE IN SOLID STATE

更新时间：2023-04-26

- RADIATION POLYMERIZATION OF ACRYLAMIDE IN SOLID STATE
- Journal of Radiation Research and Radiation Processing Vol. 3, Issue 3, Pages: 25-30(1985)
- 作者机构：
  
  1.中国科学院长春应用化学研究所
- 作者简介：
- 基金信息：
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Xu Hansheng, Zhang Zhicheng, Jin Yunzheng. RADIATION POLYMERIZATION OF ACRYLAMIDE IN SOLID STATE. [J]. Journal of Radiation Research and Radiation Processing 3(3):25-30(1985)
DOI：

Xu Hansheng, Zhang Zhicheng, Jin Yunzheng. RADIATION POLYMERIZATION OF ACRYLAMIDE IN SOLID STATE. [J]. Journal of Radiation Research and Radiation Processing 3(3):25-30(1985) DOI：

摘要

本文研究了固态丙烯酰胺辐射场内聚合和场外聚合，但得到的都是不溶的聚合物。当添加了链转移剂异丙醇，则65%的丙烯酰胺浓水溶液在冰浴中聚合，可以得到分子量超过500万，转化率达95%可溶的聚合物。

Abstract

The radiation and post-radiation polymerizations of acrylamide in solid state have been studied. But polymers were insoluble unfortunatly due to intermolecular crosslinking.,When the chain transfer agent, isopropyl alcohol, was added, which effectively inhibits the crosslinking to give water soluble polymer, 95% conversion and molecular weight more than 5×10,6, polyacrylamide were obtained at a monomer concentration 65% in ice bath.

关键词

丙烯酰胺固态聚合假固态聚合

Keywords

AcrylamideRadiation polymerization in solid stateRadiation polymerization in pseudo solid state

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