THE GAS PHASE REACTIONS OF HYDROXYL RADICALS WITH SEVERAL UNSATURATED HYDROCARBONS

Liu Andong

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THE GAS PHASE REACTIONS OF HYDROXYL RADICALS WITH SEVERAL UNSATURATED HYDROCARBONS

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- THE GAS PHASE REACTIONS OF HYDROXYL RADICALS WITH SEVERAL UNSATURATED HYDROCARBONS
- Journal of Radiation Research and Radiation Processing Vol. 8, Issue 1, Pages: 28-32(1990)
- 作者机构：
  
  北京师范大学低能核物理研究所，北京
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：1990-02，
  
  Received：16 September 1988，
- 稿件说明：
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Liu Andong. THE GAS PHASE REACTIONS OF HYDROXYL RADICALS WITH SEVERAL UNSATURATED HYDROCARBONS. [J]. Journal of Radiation Research and Radiation Processing, 1990,8(1):28-32.
DOI：

Liu Andong. THE GAS PHASE REACTIONS OF HYDROXYL RADICALS WITH SEVERAL UNSATURATED HYDROCARBONS. [J]. Journal of Radiation Research and Radiation Processing, 1990,8(1):28-32. DOI：

摘要

本文简要介绍了利用脉冲辐解技术研究OH自由基与不饱和碳氢化合物气相反应的基本原理。报道了在101325 Pa

300-1200 K温度范围内OH自由基与乙炔、乙烯、丙烯、1-丁烯，氯乙烯、丙二烯及1

3-丁二烯气相反应速度常数随温度的变化，并对这些反应的机理作了简单讨论。

Abstract

The principal of using pulse radiolysis technique to study the gas phase reactions of OH radicals with unsaturated hydrocarbons is described brifly in this paper. The temperature dependence of the rate constants of OH radicals with acetylene

ethylene

vinylchloride

propylene

1-butene

allene and 1

3-butadiene is reported. Short discussion was given to the reaction mechanism.

关键词

OH自由基脉冲辐解阿仑尼乌斯活化能动力学同位素效应反应机理

Keywords

OH radicalsPulse radiolysisArrhenius activition energyKinetic isotope effectReaction mechanism

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