GAMMA RADIATION SULFOCHLORINATION OF MIXTURE OF PARAFFINS AND NAPHTHENES (MPN) I The Study On Mechanism of Radiation Sulfochlorination

Murat; Liu Junchen; Liu Songqing; Wang Fengju; Zhao Jun

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GAMMA RADIATION SULFOCHLORINATION OF MIXTURE OF PARAFFINS AND NAPHTHENES (MPN) I The Study On Mechanism of Radiation Sulfochlorination

更新时间：2024-11-05

- GAMMA RADIATION SULFOCHLORINATION OF MIXTURE OF PARAFFINS AND NAPHTHENES (MPN) I The Study On Mechanism of Radiation Sulfochlorination
- Journal of Radiation Research and Radiation Processing Vol. 9, Issue 2, Pages: 69-73(1991)
- 作者机构：
  
  中国科学院新疆物理研究所，乌鲁木齐
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：1991-05，
  
  Received：26 February 1990，
- 稿件说明：
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Murat, Liu Junchen, Liu Songqing, et al. GAMMA RADIATION SULFOCHLORINATION OF MIXTURE OF PARAFFINS AND NAPHTHENES (MPN) I The Study On Mechanism of Radiation Sulfochlorination. [J]. Journal of Radiation Research and Radiation Processing, 1991,9(2):69-73.
DOI：

Murat, Liu Junchen, Liu Songqing, et al. GAMMA RADIATION SULFOCHLORINATION OF MIXTURE OF PARAFFINS AND NAPHTHENES (MPN) I The Study On Mechanism of Radiation Sulfochlorination. [J]. Journal of Radiation Research and Radiation Processing, 1991,9(2):69-73. DOI：

摘要

以混合烷烃为原料，采用γ辐射磺氯酰化法生产出了烷基石油磺酸钠，G

（烷基磺酰氯）

值与剂量率的关系为G=kP

-0.5

，采用电子顺磁共振、核磁共振和气相色谱／质谱／计算机联合系统等技术手段，研究了混合烷烃γ辐射磺氯酰化反应的特性，采用廉价的混合烷烃为原料合成烷基石油磺酸盐。

Abstract

Petroleum sodium sulfonates can be producted by γ-radiation sulfochlorination of MPN.

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https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=68635614&type=

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Value is proportional to inverse-square-root of radiation dose rate. According to Electron Spin Resonance

Nuclear Magnetic Resonace and GC/MS/DCS analyses

the radiation sulfochlorination mechanisms of MPN are proposed. There is a patential to synthesize sulfonates from relatively inexpensive MPN.

关键词

γ辐射磺氯酰化G值电子顺磁共振核磁共振色谱／质谱／计算机联合系统

Keywords

γ-RadiationSulfochlorinationG ValueESRNMRGC/MS/DCS

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